生物质化学工程2024，Vol.58Issue(4)：57-68,12.DOI:10.3969/j.issn.1673-5854.2024.04.008
基于香草醛的热固性树脂研究进展
Research Progress of Thermosetting Resin Based on Vanillin
摘要
Abstract
Vanillin is a commercially available monoaromatic compound,which can be produced from lignosulfonates,and has become a hot research topic in material science owing to its unique chemical structure.This review firstly introduces the research progress of vanillin-based thermosetting materials,including epoxy resins,benzoxazines,phenolic resins and(meth)acrylates,emphasizing the chemical derivatization and crosslinking process based-on the unique structure of vanillin.Then,thermosetting resins with dynamic covalent bonds are summarized with their potential applications.The aldehyde group on vanillin facilitates the introduction of dynamic acetal,imine and dithioacetal groups,while disulfide,Diels-Alder adducts and β-hydroxyl esters can be installed by choosing the cross-linking system.After summarizing their properties and applications,a perspective is provided on its sustainability over raw material availability,material preparation,recycling,and degradation.关键词
香草醛/热固性树脂/动态共价键/可回收热固性材料Key words
vanillin/thermosetting resin/dynamic covalent bond/recyclable thermosetting material分类
化学化工引用本文复制引用
冯淼,胡程程,袁亮,刘玉鹏..基于香草醛的热固性树脂研究进展[J].生物质化学工程,2024,58(4):57-68,12.基金项目
国家自然科学基金资助项目(32071724) （32071724）
