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可水分散性油墨聚氨酯树脂的制备及其性能研究

张博 石红翠 宋利青

塑料科技2024,Vol.52Issue(6):6-9,4.
塑料科技2024,Vol.52Issue(6):6-9,4.DOI:10.15925/j.cnki.issn1005-3360.2024.06.002

可水分散性油墨聚氨酯树脂的制备及其性能研究

Study on Preparation and Properties of Water-Dispersible Ink Polyurethane Resin

张博 1石红翠 1宋利青1

作者信息

  • 1. 山西省应用化学研究所(有限公司),山西太原 030027
  • 折叠

摘要

Abstract

Water-dispersible polyurethane(PU)resins were prepared with toluene diisocyanate(TDI),polyoxypropylene glycol(PPG),2,2-dimethylol propionic acid(DMPA),isophorone diamine(IPDA)and N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane(KH-792)as the main raw materials.Waterborne plastic printing inks is formulated using PU resin.The molecular structure of PU was characterized by infrared spectroscopy.The effects of KH-792 content on the thermal stability,viscosity,mechanical properties,water resistance and ink properties of PU resin were studied.The results showed that with the increase of KH-792 content,the initial thermal degradation temperature,the carbon residual rate of thermal weight loss,viscosity,tensile strength and elongation at break of PU resin increased gradually,and the water absorption first decreased and then increased.With the increase of KH-792 content,the viscosity of the prepared ink increased gradually,the fineness decreased first and then increased,and the adhesion fastness,storage stability and boiling resistance increased first and then decreased.When the amount of KH-792 was 10%,the comprehensive performance of PU resin and its ink was the best.

关键词

水分散性/油墨/聚氨酯/有机硅/耐热性/耐水性

Key words

Water-dispersion/Ink/Polyurethane/Organosilicon/Heat resistance/Water resistance

分类

化学化工

引用本文复制引用

张博,石红翠,宋利青..可水分散性油墨聚氨酯树脂的制备及其性能研究[J].塑料科技,2024,52(6):6-9,4.

基金项目

山西省重点研发计划项目(202202040201013) (202202040201013)

塑料科技

OA北大核心CSTPCD

1005-3360

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