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针对高密度聚乙烯IBC桶专用料发黄问题分析

刘洋 杜文博 杨公华 谭捷 岑静芸 郭森

塑料科技2024,Vol.52Issue(6):51-55,5.
塑料科技2024,Vol.52Issue(6):51-55,5.DOI:10.15925/j.cnki.issn1005-3360.2024.06.010

针对高密度聚乙烯IBC桶专用料发黄问题分析

Yellowing Problem Analysis in High-Density Polyethylene IBC Barrel Special Material

刘洋 1杜文博 1杨公华 1谭捷 1岑静芸 1郭森1

作者信息

  • 1. 中国石油化工股份有限公司茂名分公司研究院,广东茂名 525000
  • 折叠

摘要

Abstract

The coloration and material yellowing problem in the production of high-density polyethylene TR580M from different batches are explored and analyzed.TR580M produced in different batches in one year was selected and analyzed by molecular weight and distribution,melt flow rate(MFR),oxidation induction time(OIT),volatile organic compounds(VOC),xylene insoluble matter,ash content and torque detection during processing.The results show that compared to the other batches,the higher TR580M chroma batch has lower ash content,higher xylene insoluble matter and VOC content,and more significant MFR changes at different shear rates and higher torque increases during processing.The main reason for the yellow color is that the residual activity of the catalyst produced in this batch is high,and the insufficient protection of the antioxidant system during the processing leads to the increase of the gel content.

关键词

高密度聚乙烯/TR580M/发黄/催化剂/凝胶

Key words

High-density polyethylene/TR580M/Yellowing problem/Catalyst/Gel

分类

化学工程

引用本文复制引用

刘洋,杜文博,杨公华,谭捷,岑静芸,郭森..针对高密度聚乙烯IBC桶专用料发黄问题分析[J].塑料科技,2024,52(6):51-55,5.

塑料科技

OA北大核心CSTPCD

1005-3360

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