塑料科技2024,Vol.52Issue(6):51-55,5.DOI:10.15925/j.cnki.issn1005-3360.2024.06.010
针对高密度聚乙烯IBC桶专用料发黄问题分析
Yellowing Problem Analysis in High-Density Polyethylene IBC Barrel Special Material
刘洋 1杜文博 1杨公华 1谭捷 1岑静芸 1郭森1
作者信息
- 1. 中国石油化工股份有限公司茂名分公司研究院,广东茂名 525000
- 折叠
摘要
Abstract
The coloration and material yellowing problem in the production of high-density polyethylene TR580M from different batches are explored and analyzed.TR580M produced in different batches in one year was selected and analyzed by molecular weight and distribution,melt flow rate(MFR),oxidation induction time(OIT),volatile organic compounds(VOC),xylene insoluble matter,ash content and torque detection during processing.The results show that compared to the other batches,the higher TR580M chroma batch has lower ash content,higher xylene insoluble matter and VOC content,and more significant MFR changes at different shear rates and higher torque increases during processing.The main reason for the yellow color is that the residual activity of the catalyst produced in this batch is high,and the insufficient protection of the antioxidant system during the processing leads to the increase of the gel content.关键词
高密度聚乙烯/TR580M/发黄/催化剂/凝胶Key words
High-density polyethylene/TR580M/Yellowing problem/Catalyst/Gel分类
化学工程引用本文复制引用
刘洋,杜文博,杨公华,谭捷,岑静芸,郭森..针对高密度聚乙烯IBC桶专用料发黄问题分析[J].塑料科技,2024,52(6):51-55,5.