物理学报2024，Vol.73Issue(15)：189-198,10.DOI:10.7498/aps.73.20240663
近红外二区长波发射Na3YSi3O9:xCr3+硅酸盐及多格位占据光谱展宽
Long wavelength near-infrared Ⅱ emitting Na3YSi3O9:x Cr3+silicate and spectral broadening by multi-site occupancy
摘要
Abstract
Phosphors-converted near-infrared LED(pc-NIR LED)possesses applications in various fields including food quality analysis,night vision,biomedical imaging,and biomedicine.The design and development of broadband near-infrared(NIR)phosphors with the required properties are of decisive significance for pc-NIR LED devices.The Cr3+doped phosphors are considered to be most promising near-infrared materials for commercialization.Broadband NIR luminescent materials doped with Cr3+have attracted more and more attention due to their potential applications in NIR light sources.However,the emission wavelength of Cr3+doped phosphor is generally located in the NIR Ⅰ region of less than 850 nm,and realizing the NIR Ⅱ region emission is still a challenge.In this work,a series of Cr3+doped Na3YSi3O9 new silicate phosphors is prepared by solid-state method in N2 atmosphere at 1150℃ for 8 h.We take advantages of the silicate nature and the multi octahedral sites suitable for Cr3+in the studied Na3YSi3O9 materials to redshift and broaden the spectrum.The phase,crystal structure,microstructure,photoluminescence,main emission peak decay and thermal stability of the samples are systematically studied.The results show that the prepared samples are pure phases,with uneven morphology,slight agglomeration,and the sizes in the micrometer range.The Cr3+is located in the weak crystal field environment of Na3YSi3O9 lattice,with a Dq/B value of 2.29.Under the excitation of blue light at a wavelength of 485 nm,the strongest emission peaks of Na3Y1-xSi3O9:x Cr3+phosphors are located at 984 nm(NIR Ⅱ region),which is longer than those of most Cr3+activated phosphors.Due to the multi-site occupation of Cr3+in the lattice,the full width at half maximum(FWHM)of the emission spectrum is as high as 183 nm.The optimal doping concentration of Na3Y1-xSi3O9:x Cr3+is 3％,and the quenching mechanism is the dipole-dipole interaction between Cr3+ions.Fluorescence decay curves show that the luminescence lifetime of Na3Y0.97 Si3O9:0.03Cr3+sample gradually decreases with the increase of doping concentration and temperature.The results of the temperature-dependent spectra show that the emission intensity decreases in a temperature range from 298 K to 423 K,and the activation energy ΔE of Cr3+is 0.157 eV.关键词
硅酸盐/Cr3+/宽带近红外/多格位Key words
silicate/Cr3+/broadband near-Infrared/multi-sites引用本文复制引用
龚长帅,王建通,王渤文,薛绪岩,王雪娇..近红外二区长波发射Na3YSi3O9:xCr3+硅酸盐及多格位占据光谱展宽[J].物理学报,2024,73(15):189-198,10.基金项目
辽宁省教育厅自然科学基金(批准号:JYTMS20231627)和辽宁省科技厅自然科学基金(批准号:2020-MS-286)资助的课题.Project supported by the Natural Science Foundation of the Educational Department of Liaoning Province,China(Grant No.JYTMS20231627)and the Natural Science Foundation of Liaoning Provincial Department of Science and Technology,China(Grant No.2020-MS-286). （批准号:JYTMS20231627）
