白云鄂博矿区矿石中磁铁矿及萤石的X射线粉晶衍射半定量分析方法及矿物三维空间分布模型OA北大核心CSTPCD
Semi-quantitative Analysis of Magnetite and Fluorite by X-ray Powder Crystal Diffraction and Three-dimensional Distribution Model of Minerals in Bayan Obo Mining Area
白云鄂博超大型铁-稀土-铌矿床,伴生大量萤石等资源.现阶段,矿山资源评价采用的是多元素定量分析方法,该方法存在不能客观的表征出可用资源的矿物组成和赋存状态的缺陷.为了较为准确地确定元素赋存形式及磁铁矿、萤石矿物含量,本研究选用粉晶X射线衍射K值法定量分析法,通过以白云鄂博白云石为参比物质分别调配 1∶1比例产自白云鄂博的磁铁矿、萤石与白云石单矿物样品,获得以白云石为参比的磁铁矿参比强度KFe3O41=0.61、萤石参比强度KCaF21=2.51,同时,精选了白云鄂博其他常见共生矿物的K值,以实现对白云鄂博不同矿石类型中矿物含量的半定量分析,通过测试已知标样验证了改进优化K值的正确性和适用性.利用大量实际岩心矿石样品矿物定量分析数据,通过克里金插值法获得白云鄂博主矿磁铁矿和萤石矿物的空间分布三维模型,初步呈现了资源矿物的空间分布特征,推测在矿区深部仍存在巨大的找矿潜力.X射线粉晶衍射定量分析技术直接对可回收资源的矿物半定量分析研究,为矿山精准分采和资源综合利用探索了新的解决思路,也为选矿流程的优化提供的重要的技术参考.
Bayan obo super large Fe-RE-Nb deposit,associated with a large amount of fluorite and other re-sources.At present,the multi-element quantitative analysis method is used in the evaluation of mine resources,which can not objectively characterize the mineral composition and occurrence state of available resources.In order to determine the occurrence form of elements and the content of magnetite and fluorite minerals more ac-curately,this study uses the powder crystal X-ray diffraction K-value method for quantitative analysis,and uses dolomite as the reference material to prepare 1∶1 proportion of single mineral samples of magnetite,fluorite and dolomite produced in Bayan Obo,the reference intensity of magnetite with dolomite as the reference is KFe3O4=0.61,and the reference intensity of fluorite is KCaF2=2.51.At the same time,the K value of other com-mon co-minerals in Bayan Obo is selected.In order to realize the semi-quantitative analysis of the mineral con-tent in different ore types of Bayan Obo,the correctness and applicability of the improved optimization K are verified by testing the known standard samples.Based on the quantitative analysis data of a large number of ac-tual core ore samples,a three-dimensional model of spatial distribution of magnetite and fluorite minerals in Bayan Obo main mine was obtained by Kriegin interpolation method,and the spatial distribution characteristics of resource minerals were preliminarily presented.It is speculated that there is still a huge prospecting potential in the deep part of the mine area.X-ray powder diffraction quantitative analysis technology can directly study the semi-quantitative analysis of minerals in recoverable resources,which explores a new solution for precise mining and comprehensive utilization of resources,and also provides an important technical reference for the optimization of mineral processing process.
孙宁岳;闫国英;李国武;王昭静;申俊峰;徐渴鑫;孟文祥;李凤坤
中国地质大学(北京) 科学研究院晶体结构实验室,北京 100083包头钢铁(集团)有限责任公司矿山研究院(有限责任公司),内蒙古 包头 014010中国地质大学(北京) 地球科学与资源学院 成因矿物学研究中心,北京 100083
地质学
白云鄂博磁铁矿萤石X射线粉晶衍射矿物组分半定量分析
Bayan Obomagnetitefluoritepowder X-ray diffractionmineral compositionssemi-quan-titative analysis
《西北地质》 2024 (004)
113-120 / 8
包头钢铁(集团)有限责任公司矿山研究院(有限责任公司)2021年A类重点项目"白云鄂博稀土-铌-铁资源矿物标型学研究(BGKY-ZH-2021-Z-017)"资助.
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