松辽盆地海力锦铀矿床成矿流体特征OACSTPCD
Ore-forming Fluid Characteristics of Hailijin Uranium Deposit in Songliao Basin:Petrogeochemistry Evidence From Ore-bearing Sandstones
松辽盆地西南部砂岩型铀矿床成因是制约盆地西南部铀矿勘查找矿突破的关键因素之一.文章以海力锦铀矿床为研究对象,对其岩石地球化学特征开展了系统研究,主要获得了以下几点认识:1)各地球化学分带砂岩主量元素、稀土元素差别不大,指示含矿层砂岩具有一致的物质来源;但U和Re、Mo、Co、Cr、Pb、Zn、Ni等微量元素在矿石中的含量明显高于原生红色带、弱还原带和中等还原带砂岩,表明铀成矿期发生了这些元素的输入.这些元素通常来自于深部具有一定温度的还原性流体,进一步指示成矿流体可能来自于深部.2)灰色还原带砂岩及矿石中高岭石的含量明显高于原生红色带、弱还原带和中等还原带砂岩,沥青铀矿常吸附于高岭石表面或微孔隙之中,结合研究区姚家期古气候特征及高岭石成因,分析认为灰色还原带砂岩及矿石中异常富集的这部分高岭石为后生成因,与成矿流体关系密切,含矿层砂岩在铀成矿期经历了酸性流体的改造作用.3)结合松辽盆地西南部钱家店地区下白垩统九佛堂组、沙海组广泛分布的富铀烃源岩,认为海力锦铀矿床成矿流体可能来自深部的富铀还原性流体,在成矿期沿连通姚家组下段目标层的断裂向上渗出,随着温度、压力的降低及体系所处环境由还原转变为氧化环境,导致铀在流体中的溶解度急剧降低而析出沉淀下来,最终富集成矿.本次研究为松辽盆地西南部砂岩型铀矿床成因研究提供了新思路,具有重要的理论和实际意义.
The genesis of sandstone-type uranium deposits in the southwestern Songliao Basin is one of the key factors that restrict the breakthrough of uranium exploration.This article takes the Hailijin uranium deposit as the research object and carries out a systematic study on its petrogeochemical characteristics.The main understanding obtained is as follows:(1)The major elements and REEs of sandstone in various geochemical zones are not significantly different,indicating that the sandstone of the ore-bearing layer has a consistent material source.However,the contents of trace elements such as U and Re,Mo,Co,Cr,Pb,Zn,and Ni in the ores are significantly higher than those in sandstone of native red zone,weakly reducing zone,and moderately reducing zone,indicating that these elements were immigrated during the uranium mineralization period.These elements usually derive from deep reducing fluids with a certain temperature,further indicating that the ore-forming fluids may come from the deep part.(2)The content of kaolinite in gray reducing zone and ores is significantly higher than that in sandstone of native red zone,weakly reducing zone and moderately reducing zone.SEM analysis indicated that pitchblende was often adsorbed on the surface or in the micropores of kaolinite.Combined with the paleoclimatic characteristics of Yaojia period in the study area and the genesis of kaolinite,it was believed that the abnormally enriched kaolinite in gray reducing zone and ores was of epigenetic genesis and closely related to ore-forming fluids.The sandstone of the ore-bearing layer underwent acidic fluid transformation during the uranium mineralization period.(3)Combined with the uranium-rich hydrocarbon source rocks widely distributed in Jiufotang Formation and Shahai Formation of the Lower Cretaceous in Qianjiadian area,it was believed that the ore-forming fluids of the Hailijin uranium deposit might originated from deep uranium-rich reducing fluids.During the mineralization period,they exuded upward along the fault connecting the target layer of the lower member of Yaojia Formation.With the decrease of temperature and pressure,and the change of the environment from reduction to oxidation,the solubility of uranium in the fluid decreased sharply and precipitated,and finally accumulated into mineralization.This study provided a new idea for the genesis of sandstone-type uranium deposits in the southwestern Songliao Basin,which is of important theoretical and practical significance.
张康;田明明;马娜;沈达
中国铀业股份有限公司,北京 100013核工业北京地质研究院,北京 100029中核铀业有限责任公司,北京 100013
地质学
岩石地球化学成矿流体红杂色沉积建造渗出铀成矿作用松辽盆地
petrogeochemistryore-forming fluidred-mottled sedimentary constructionexudative uranium metallogenySongliao Basin
《铀矿地质》 2024 (004)
591-602 / 12
叶企孙科学基金"砂岩型铀矿含矿灰色砂体成因研究"(编号:U2341292)资助.
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