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Dy3+,Tb3+共掺氮化铝薄膜结构与发光特性OA北大核心CSTPCD

Structure and cathodoluminescence properties of Dy3+and Tb3+doped AlN films

中文摘要英文摘要

通过离子注入方法,首次将Dy3+和Tb3+共掺入氮化铝(AlN)薄膜,并研究了其晶体结构、阴极荧光和能量传递机制.拉曼光谱(Raman)和X射线衍射(XRD)结果显示,在Tb3+剂量一定的情况下,Dy3+的注入会导致晶格内部压应力增大,随着Dy3+的持续注入,一部分点缺陷发生复合,内部部分压应力会得到释放.阴极荧光光谱(CL)显示,高剂量Tb3+注入下,随着Dy3+剂量的增加,Tb3+的发射强度与Dy3+的发射强度呈现出不同的变化趋势.进一步分析表明可能存在Tb3+的5D4→7F6 至Dy3+的6H15/2→4F9/2 的共振能量传递.通过研究发现在不同Tb3+和Dy3+注入剂量下,样品的发光颜色在黄绿色与橙黄色之间转变,色温在 4042~5119K范围变化.由上述研究结果可知,通过改变Tb3+与Dy3+共注入的剂量比可以有效调控材料的发光色坐标与色温.

For the first time,Tb3+and Dy3+co-doped AlN films were prepared using ion implantation,and their crystal structure,cathodoluminescence properties and energy transfer mechanism were investigated.Ra-man scattering and X-ray diffraction results indicate that ion implantation of Dy3+has caused increased com-pressive stress within the internal lattice when the dosage of Tb3+remains constant.Continuous implantation led to the recombination of some point defects,resulting in a partial release of internal compressive stress.Cathodoluminescence spectra demonstrated that with high-dose Tb3+implantation,the emission intensities of Tb3+and Dy3+exhibited different trends with increasing Dy3+dosage.We propose the existence of a reson-ance energy transfer from Tb3+ions 5D4→7F6 to Dy3+ions 6H15/2→4F9/2 in AlN films.Finally,we observe that under different implantation dose of Dy3+ions to Tb3+ions,the emission color of the sample shifts between yellow-green and orange-yellow,with color temperatures ranging from 4042 to 5119K.Adjusting the dose ratio of Dy3+to Tb3+enables effective control of chromaticity coordinates and color temperatures.

罗璇;孟河辰;王晓丹;陈子航;曾雄辉;高晓冬;郑树楠;毛红敏

苏州科技大学物理科学与技术学院,江苏苏州 215009中国科学院苏州纳米技术与纳米仿生研究所,江苏苏州 215123

电子信息工程

镝离子铽离子氮化铝发光特性能量传递

dysprosium ionsterbium ionsaluminum nitrideluminescent propertiesenergy transfer

《中国光学(中英文)》 2024 (004)

733-741 / 9

国家自然科学基金资助项目(No.61974158,No.61306004);江苏省自然科学基金(No.BK20191456,No.BK20221263);江苏省"十四五"光学工程重点学科项目资助(No.2021135);江苏省研究生科研创新计划项目资助(No.KYCX22_3266)Supported by National Natural Science Foundation of China(No.61974158,No.61306004);Natural Science Fund of Jiangsu Province(No.BK20191456,No.BK20221263);Jiangsu Key Disciplines of the Fourteenth Five-Year Plan(No.2021135);Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX22_3266)

10.37188/CO.2023-0219

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