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纳米黏土与二氧化硅协同改性聚乳酸研究

王杰 辛德华 李晖 蒋洪石 周洪福 赵建国

中国塑料2024,Vol.38Issue(7):43-48,6.
中国塑料2024,Vol.38Issue(7):43-48,6.DOI:10.19491/j.issn.1001-9278.2024.07.008

纳米黏土与二氧化硅协同改性聚乳酸研究

Effect of hybrid reinforcement of nanoclay and silica on properties of poly(lactic acid)

王杰 1辛德华 1李晖 1蒋洪石 1周洪福 2赵建国3

作者信息

  • 1. 运城学院应用化学系,山西 运城,044000
  • 2. 北京工商大学化学与材料工程学院,北京,100048
  • 3. 煤基生态碳汇技术教育部工程研究中心,山西 大同,037009
  • 折叠

摘要

Abstract

PLA was adopted as a polymeric matrix to prepare PLA/nanoclay composites.The effect of the amount of nanoclay together with 2 phr SiO2 as a hybrid reinforcement on the structures and properties of the composites were inves-tigated.The results indicated that the crystallization behaviors,melt processability,mechanical toughness,and gas barri-er property of the PLA composites were significantly improved.The PLA composite with 2 phr SiO2 and 4 phr clay ex-hibited good filler dispersion,ductile fracture,and good gas barrier property.Compared to pure PLA,the PLA compos-ites presented an increase in elongation at break by 151%and in impact strength by 74.1%.Their oxygen and water va-por permeability coefficients were reduced by 67.4%and 65.0%,respectively.The excessive amount of clay was dis-advantageous to the toughness and also generated a slightly influence on gas barrier.

关键词

聚乳酸/协同填充/力学性能/阻隔性能

Key words

poly(lactic acid)/hybrid reinforcement/mechanical property/gas barrier property

分类

化学化工

引用本文复制引用

王杰,辛德华,李晖,蒋洪石,周洪福,赵建国..纳米黏土与二氧化硅协同改性聚乳酸研究[J].中国塑料,2024,38(7):43-48,6.

基金项目

煤基生态碳汇技术教育部工程研究中心开放基金 ()

石墨烯林业应用国家林业和草原局重点实验室开发基金 ()

运城市科技计划项目(YCKJ-2022045) (YCKJ-2022045)

运城学院化学重点学科建设经费 ()

中国塑料

OA北大核心CSTPCD

1001-9278

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