中南大学学报（自然科学版）2024，Vol.55Issue(6)：2061-2073,13.DOI:10.11817/j.issn.1672-7207.2024.06.001
羟肟酸捕收剂的结构优化及应用研究进展
Research progress on structure optimization and application of hydroxamic acid collector
摘要
Abstract
As a traditional anionic chelating collector,hydroxamic acid is widely used in the flotation of oxide minerals and rare earth minerals.In recent years,with the development of the molecular design theory of flotation reagents and the in-depth study of the principle of action of flotation reagents,more and more new hydroxamic acid collectors have been developed and applied in mineral flotation.Hydroxamic acid collectors are composed of polar and non-polar groups,and the flotation performance of the collectors can be enhanced by optimizing the structure of these two groups.For the polar group,it can be optimized by introducing hydroxamic group,nitrogen-containing group and sulfide ether group;for the nonpolar group,it can be optimized by choosing suitable hydrocarbon chain structure and introducing electrophilic or electrophobic group.There are two interaction models between metal-based hydroxyxamic acid complexes and mineral surfaces,namely the pre-adsorption activated flotation model and the metal ion interface pre-assembly model.关键词
羟肟酸/矿物浮选/分子结构设计/金属离子配合物Key words
hydroxamic acid/mineral flotation/molecular structure design/metal-ion complex分类
矿业与冶金引用本文复制引用
邓朝政,程永彪,付君浩,曾礼强,崔曼,刘卫平,陈文胜,韩海生..羟肟酸捕收剂的结构优化及应用研究进展[J].中南大学学报（自然科学版）,2024,55(6):2061-2073,13.基金项目
国家自然科学基金委优秀青年基金资助项目(52122406) （52122406）
国家"十四五"重点研发计划项目(2022YFC2905104,2022YFC2905105)(Project(52122406)supported by Excellent Youth Program of National Natural Science Foundation of China （2022YFC2905104,2022YFC2905105）
Projects(2022YFC2905104,2022YFC2905105)supported by the National Key Research and Development Program of the 14th Five-Year Plan （2022YFC2905104,2022YFC2905105）
