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高导压铸Al-La合金组织及性能研究OACSTPCD

Study on Microstructure and Properties of High-Conductivity Die-Cast Al-La Alloys

中文摘要英文摘要

研究了La含量(4%、6%、8%、10%)对压铸Al-La合金的微观组织、力学性能以及导电导热性能的影响.La在铝基体中的固溶度极小,易富集于α-Al凝固界面前沿而造成成分过冷,降低α-Al周围液相的结晶温度,进而抑制α-Al的生长而实现细化.凝固过程中生成的Al11La3第二相不仅可以强化合金,还可作为α-Al的异质形核点以实现细化,这得益于其与α-Al基体5.96%的较小错配度.随着La含量从4%增加到10%,合金的屈服强度与抗拉强度分别从48.6 MPa、113.9 MPa提升到92.3 MPa、186.7 MPa,但伸长率从26.1%降低至9.6%.此外,Al-La合金的热导率、电导率随La含量的增加大致呈线性下降趋势,分别从207.8 W/(m·K)、32.0 MS/m下降至 173.1 W/(m·K)、26.1 MS/m.

The effects of La contents(4%,6%,8%,10%)on the microstructures,mechanical properties,thermal and electrical conductivities of die-cast Al-La alloys were investigated.The solid solubility of lanthanum in aluminum matrix was very small,and it was easy to enrich in the front of the solidification interface of α-Al,resulting in component supercooling,reducing the crystallization temperature of the liquid around α-Al,and then inhibiting the growth of α-Al to achieve refinement.The secondary phase Al11La3 produced during solidification process not only improved the strength of the alloy,but also could be used as heterogeneous nucleation point of α-Al to achieve refinement,which was benefit from the small lattice mismatch of 5.96%.With the increase of La content from 4%to 10%,the yield strength and ultimate tensile strength of the alloy increased from 48.6 MPa and 113.9 MPa to 92.3 MPa and 186.7 MPa,respectively,but the elongation decreased from 26.1%to 9.6%.In addition.It was found that the thermal and electrical conductivities decreased linearly with the increase of La content,from 207.8 W/(m·K),32.0 MS/m to 173.1 W/(m·K),26.1 MS/m,respectively.

裘珂可;周其良;郭潘狄;彭暄霖;胡波;李德江;曾小勤

浙江钜丰科技股份有限公司,浙江嵊州 312400上海交通大学材料科学与工程学院,上海 200240

金属材料

Al-La合金第二相力学性能电导率热导率

Al-La alloysecondary phasemechanical propertieselectrical conductivitythermal conductivity

《铸造》 2024 (007)

947-954 / 8

绍兴市科技计划项目(2022B41020).

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