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高性能聚酯-醚二醇的合成及应用

李剑锋 公维英 杜金彤 张潇飒

塑料科技2024,Vol.52Issue(7):79-83,5.
塑料科技2024,Vol.52Issue(7):79-83,5.DOI:10.15925/j.cnki.issn1005-3360.2024.07.017

高性能聚酯-醚二醇的合成及应用

Synthesis and Application of High Performance Polyester-Ether Glycol

李剑锋 1公维英 1杜金彤 2张潇飒3

作者信息

  • 1. 山东一诺威新材料有限公司,山东淄博 255075
  • 2. 山东玻纤集团股份有限公司玻纤工业技术研究院,山东临沂 276400
  • 3. 沈阳化工大学理学院,辽宁沈阳 110142
  • 折叠

摘要

Abstract

Polyester-ether glycol was synthesized with poly(polyol adipate)as starting agent,epoxy alkane as the polymerization monomer,and alkali metal as catalyst.The effects of catalyst dosage on the polymerization was discussed,and its structure was characterized by FTIR and GPC.The self-made polyester-ether glycol was used to prepare polyurethane high-resilience foam and polyurethane elastomer,and the effects of polyester-ether glycol on their mechanical properties were studied.The results showed that the optimum catalyst concentration was 0.6% .When polyester-ether glycol was applied to polyurethane high resilience foam with the addition amount of 15%,it had a significant effect on improving the mechanical properties of the products.Compared with traditional propylene glycol polyether,polyurethane synthesized with polyester-ether glycol had significant advantages in mechanical properties.

关键词

聚酯-醚多元醇/聚氨酯高回弹泡沫/力学性能

Key words

Polyester-ether polyol/Polyurethane high resilience foam/Mechanical property

分类

化学化工

引用本文复制引用

李剑锋,公维英,杜金彤,张潇飒..高性能聚酯-醚二醇的合成及应用[J].塑料科技,2024,52(7):79-83,5.

基金项目

辽宁省教育厅面上项目(LJKMZ20220790) (LJKMZ20220790)

塑料科技

OA北大核心CSTPCD

1005-3360

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