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TiO2掺杂对ZnO压敏电阻性能的影响OA

Effect of TiO2 Doping on Properties of ZnO Varistor

中文摘要英文摘要

通过材料配方中掺杂不同的TiO2探究其对ZnO压敏电阻综合电气性能及退化行为的影响.实验对成品的晶相组成、微观结构、综合电学性能等进行了测试与表征.研究发现当掺杂量为0.4%(摩尔分数,下同)时的样品E4体现了整体较优的表现,其电位梯度由EO的180.2 V/mm降低至147.3 V/mm,α=83.8,IL=0.38 pA.随着20次20 kA的电流冲击,电位梯度均呈下降的趋势,其中掺杂了TiO2的样品中E4表现最佳,%△E1mA+和%△E1mA-分别为-5.64%和-4.71%,老化系数Kct值为0.75,功耗降低程度较大,表现出良好的电学性能,更适合在电路中长期工作.

The effect of TiO2 doping on the comprehensive electrical properties and degradation behavior of ZnO varistor were investigated.The crystal phase composition,microstructure and comprehensive elec-trical properties of the product were tested and characterized.It is found that the sample E4 with 0.4%(mol fraction,the same below)doping exhibits better overall performance,and its potential gradient de-creases from 180.2 V/mm to 147.3 V/mm,α=83.8,IL=0.38 mA.With 20 pulses of 20 kA,the poten-tial gradient decreased,and the samples doped with TiO2 showed the best performance in E4.-5.64%for%△E1mA+and-4.71%for%△E1mA-,the aging coefficient Kct value is 0.75,the power consumption is greatly reduced,showing good electrical performance,and the invention is more suitable for long-term operation in circuits.

吴育聪;任鑫;孙岩;杨莉禹;宁宇;姚政

上海大学理学院纳米科学与技术研究中心,上海2000444

ZnO压敏电阻TiO2电学性能

ZnO varistorTiO2electrical properties

《电瓷避雷器》 2024 (004)

64-70 / 7

10.16188/j.isa.1003-8337.2024.04.008

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