高校化学工程学报2024，Vol.38Issue(4)：523-537,15.DOI:10.3969/j.issn.1003-9015.2024.04.001
纤维素直接制备5-羟甲基糠醛的研究进展
Review on the preparation of 5-hydroxymethylfurfural by cellulose hydrolysis
摘要
Abstract
5-hydroxymethylfurfural(HMF)is an important bio-based platform chemical and was chosen as one of the top 12 value-added bio-based chemicals by the U.S.Department of Energy.The effective method for preparation HMF is the acid-catalyzed dehydration of hexoses which are limited in resources.Cellulose is widely available in nature.Using cellulose for HMF synthesis avoids the isolation of monosaccharides,and is considered as more cost-effective.Cellulose is low in reactivity and insoluble in water and general organic solvents due to its special chemical structure.The first significant barrier for the conversion of cellulose to HMF is the hydrolysis of cellulose.Based on cellulose structure and the mechanism of catalytic conversion of cellulose into HMF,known and emerging pretreatment methods,solvent systems,and catalyst systems in the conversion of cellulose into HMF in recent years are summarized.This review aims to provide references for further in-depth development of HMF production directly from cellulose and guidance for future conversion.关键词
纤维素/5-羟甲基糠醛/催化剂/溶剂/预处理Key words
cellulose/5-hydroxymethylfurfural/catalyst/solvents/pretreatment分类
化学化工引用本文复制引用
洪梅,何莉萍,朱军凯,郭雨轩,朱薇璇..纤维素直接制备5-羟甲基糠醛的研究进展[J].高校化学工程学报,2024,38(4):523-537,15.基金项目
林产化学与工程国家民委重点实验室暨广西林产化学与工程重点实验室/协同创新中心开放课题资助项目(GXFK2308). （GXFK2308）
