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重金属地质高背景区土壤Se的地球化学特征及富Se耕地综合评价OA北大核心CHSSCDCSTPCD

Geochemical Characteristics of Soil Se in Heavy Metal Geological High Background Area and Comprehensive Evaluation of Se-Rich Cultivated Land

中文摘要英文摘要

为了合理保护和利用富Se耕地资源,为重金属地质高背景区富Se农产品的安全开发提供科学依据,以重庆市黔江区白土乡为例,采集74份耕地土壤(0~20 cm)及水稻籽实样品,分析稻谷及土壤中Se和重金属(Cd、Hg、Pb、As、Cr、Cu、Zn和Ni)含量,同时分析土壤中养分元素及氧化物含量,研究土壤及稻谷中各元素的地球化学特征,并开展富Se耕地综合评价.结果显示,研究区土壤环境综合质量等级以三等(轻度污染)和四等(中度污染)为主,面积占比分别为41.65%和50.71%,污染因子为Cd.土壤Se平均含量为0.91 mg·kg-1,含量介于0.4~3.0 mg·kg-1之间的点位占比为97.29%,土壤Se资源丰富.研究区耕地土壤总体养分条件良好,但部分区域存在单元素缺乏问题,以K缺乏最为显著.耕地土壤重金属和Se含量主要与灰岩、炭质页岩(夹煤线)的风化成土有关.此外,农业活动会造成耕地土壤Cd和As的输入.研究区糙米富Se率为100%,糙米Cd超标率为7.4%,土壤pH值是影响稻谷吸收土壤Cd和Se的主控因素,中碱性条件有利于水稻富集Se而抑制其对Cd的吸收.研究区富Se耕地综合等级以二等为主,面积占比为95.68%,适宜开展富Se资源开发利用.可根据各耕地地块单项指标得分情况,通过养分元素补充、土壤酸碱度调节等措施,趋利避害利用土壤富Se资源,对部分不适宜开展富Se资源开发利用的耕地,可进行种植结构调整.

In order to rationally protect and utilize Se-rich cultivated land resources and provide scientific basis for the safe development of Se-rich agricultural products in heavy metal geological high background area,74 sets of soil(0-20 cm)and rice seed samples were collected in Baitu Township,Qianjiang District,Chongqing.The contents of Se and heavy metals(Cd,Hg,Pb,As,Cr,Cu,Zn and Ni)in paddy and soil,as well as the contents of nutrient elements and oxides in soil were analyzed,the geochemical characteristics of various elements were study and the Se rich farmland was compre-hensively evaluation.The results show that the comprehensive quality of soil environment in the study area was mainly in grade 3(mild contamination)and grade 4(middle level pollution),with the area proportion of 41.65%and 50.71%,re-spectively,and the pollution factor was mainly the element Cd.The average content of soil Se was 0.91 mg·kg-1,and 97.29%of the sites with contents between 0.4 and 3.0 mg·kg-1,indicating Se resource is rich in the soil.The overall nutrient condition of cultivated soil in the study area is good,but there is a problem of single element deficiency in some areas,especially K deficiency.The contents of heavy metals and Se in cultivated soil are mainly related to the weathering of limestone and carbonaceous shale(coal line).In addition,agricultural activities can cause the input of Cd and As in cultivated soil.In the study area,the Se enrichment rate of brown rice was 100%,and the Cd excess rate of brown rice was 7.4%.Soil pH is the main factor affecting the absorption of Cd and Se by paddy,and the medium alkaline condition was conducive to the Se enrichment of rice and inhibited the absorption of Cd.The comprehensive grade of rich Se cultivat-ed land in the study area is mainly second class,and the area accounts for 95.68%,which is suitable for the development and utilization of rich Se resources.According to the scores of individual indexes of each cultivated land plot,the soil rich in Se resources can be used to seek advantages and avoid disadvantages through nutrient element supplement and soil pH adjustment,and the planting structure could be adjusted for those cultivated lands that are not suitable for the development and utilization of Se rich resources.

刘力;张传华;张凤太;邓炜;刘燕

重庆理工大学管理学院,重庆 400054重庆理工大学管理学院,重庆 400054||重庆铁路投资集团有限公司,重庆 400025重庆理工大学管理学院,重庆 400054||重庆市规划和自然资源调查监测院,重庆 401120

环境科学

耕地土壤重金属Se地球化学特征综合评价

cultivated soilheavy metalsSegeochemical characteristicscomprehensive evaluation

《生态与农村环境学报》 2024 (008)

996-1005 / 10

国家社会科学基金重点项目(20AJY005);重庆市社科规划一般项目(2022NDYB80);2023年重庆市教育委员会人文社会科学研究规划一般项目(23SKGH256)

10.19741/j.issn.1673-4831.2023.0888

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