电池2024，Vol.54Issue(4)：461-466,6.DOI:10.19535/j.1001-1579.2024.04.005
氮硫共掺杂中空纳米炭瓶的可控合成
Controllable synthesis of nitrogen and sulfur co-doped hollow carbon nanobottles
摘要
Abstract
Heteroatom-doped carbon materials have attracted more and more attention due to their excellent electrochemical performance.Using biomass-based compounds (fructose) as carbon source,sodium oleate and three-segment copolymers as soft templates,combined with hydrothermal carbonization method,nitrogen and sulfur co-doped hollow carbon nanoparticles with the unique bottle-like structure are synthesized in situ and controlled.The microscopic morphology,elemental composition and elemental binding morphology of the carbon nanoparticles are analyzed.Carbon nanoparticles have a hollow bottle-like structure and are doped with N/S elements.Based on the microstructure,the evolution mechanism of the growth of the material from the hollow bottle-like structure to the solid peanut-like structure is obtained.In 6 mol/L KOH solution,the electrode prepared by the material has a specific capacitance of 133.2 F/g at a current of 1 A/g in 0-1 V,the capacitance retention rate is 90％ after 1000 cycles at a current of 10 A/g.关键词
超级电容器/电极材料/碳材料/纳米材料/氮硫共掺杂/软模板/水热法/纳米炭瓶Key words
supercapacitor/electrode material/carbon material/nanomaterial/nitrogen and sulfur co-doping/soft template/hydrothermal method/carbon nanobottle分类
信息技术与安全科学引用本文复制引用
李晓芳,陈晨,陈卓,文清清..氮硫共掺杂中空纳米炭瓶的可控合成[J].电池,2024,54(4):461-466,6.基金项目
湖北省自然科学基金(2022CFB741) （2022CFB741）
