东华大学学报（英文版）2024，Vol.41Issue(4)：365-376,12.DOI:10.19884/j.1672-5220.202404012
介孔碳纳米纤维负载有序PtFe合金纳米颗粒用于电催化硝酸盐还原产氨
Mesoporous Carbon Nanofibers Loaded with Ordered PtFe Alloy Nanoparticles for Electrocatalytic Nitrate Reduction to Ammonia
摘要
Abstract
Highly dispersed bimetallic alloy nanoparticle electrocatalysts have been demonstrated to exhibit exceptional performance in driving the nitrate reduction reaction(NO3RR)to generate ammonia(NH3).In this study,we prepared mesoporous carbon nanofibers(mCNFs)functionalized with ordered PtFe alloys(O-PtFe-mCNFs)by a composite micelle interface-induced co-assembly method using poly(ethylene oxide)-block-polystyrene(PEO-b-PS)as a template.When employed as electrocatalysts,O-PtFe-mCNFs exhibited superior electrocatalytic performance for the NO3RR compared to the mCNFs functionalized with disordered PtFe alloys(D-PtFe-mCNFs).Notably,the NH3 production performance was particularly outstanding,with a maximum NH3 yield of up to 959.6 μmol/(h·cm2).Furthermore,the Faraday efficiency(FE)was even 88.0％at-0.4 V vs.reversible hydrogen electrode(RHE).This finding provides compelling evidence of the potential of ordered PtFe alloy catalysts for the electrocatalytic NO3RR.关键词
有序PtFe合金/介孔碳纳米纤维/硝酸根还原/产氨反应Key words
ordered PtFe alloy/mesoporous carbon nanofiber(mCNF)/nitrate reduction reaction(NO3RR)/ammonia(NH3)production reaction分类
化学化工引用本文复制引用
谢梦,罗维,邱鹏鹏..介孔碳纳米纤维负载有序PtFe合金纳米颗粒用于电催化硝酸盐还原产氨[J].东华大学学报（英文版）,2024,41(4):365-376,12.基金项目
National Natural Science Foundation of China(Nos.52225204,52173233 and 52202085) （Nos.52225204,52173233 and 52202085）
Innovation Program of Shanghai Municipal Education Commission,China(No.2021-01-07-00-03-E00109) （No.2021-01-07-00-03-E00109）
Natural Science Foundation of Shanghai,China(No.23ZR1479200) （No.23ZR1479200）
"Shuguang Program"Supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission,China(No.20SG33) （No.20SG33）
Fundamental Research Funds for the Central Universities,China(No.2232024Y-01) （No.2232024Y-01）
DHU Distinguished Young Professor Program,China(Nos.LZA2022001 and LZB2023002) （Nos.LZA2022001 and LZB2023002）
