基于碳/MOFs及其衍生物复合材料在锂硫电池阴极中的应用OA北大核心CSTPCD
Application of carbon-doped MOFs and their derivatives in lithium-sulfur batteries
锂硫电池(lithium-sulfur batteries,LSBs)因其理论能量密度高、价格低廉而被认为是一种最具前景的新型电池体系之一.然而,实际应用中存在导电性差、体积易膨胀,以及循环稳定性差等问题.金属有机框架(metal organic frameworks,MOFs)因其高比表面积与孔隙率特性在LSBs中有效抑制硫溶解,提升硫利用率,实现高循环稳定性,而结合导电性优异的碳材料则进一步优化了整体导电性能.因此,基于碳/MOFs及其衍生物的复合物材料在LSBs阴极中的应用成为当前LSBs的研究热点.综述了近年来有关碳/MOFs及其衍生物的复合物材料在LSBs正极材料方面取得的一些研究进展,并对MOFs及其衍生物在LSBs电极中的应用进行了总结和展望.
Lithium-sulfur batteries (LSBs) are considered to be one of the most promising new battery systems due to their high theoretical energy density and low price. However,there are some problems in practical application,such as poor electrical conductivity,easy volume expansion and poor cycle stability. Metal organic frameworks (MOFs) are used for LSBs due to the characteristics of large spe-cific surface area and high porosity,which can inhibit the dissolution of sulfur and improve the utili-zation rate of sulfur to achieve high cyclic stability of LSBs. Adding carbon materials with excellent electrical conductivity can improve the overall conductivity of the electrode. Therefore,the applica-tion of composite materials based on C/MOFs and their derivatives in LSBs cathodes has become a current research hotspot in LSBs. This article summarized some recent research progress on C/MOFs and their derivatives in LSBs cathode materials. The application of MOFs and their deriva-tives in LSBs electrodes was summarized and prospected.
辛娜;王亚平;王天鸶;栗欢欢
江苏大学汽车工程研究院,江苏镇江212013江苏大学材料科学与工程学院,江苏镇江212013
动力与电气工程
锂硫电池MOFs碳材料金属化合物
lithium-sulfur batteryMOFscarbon materialsmetal compound
《电源技术》 2024 (008)
1394-1407 / 14
江苏省自然科学基金项目(BK20201426,BK20210765);镇江市科技计划项目(CQ2022004)
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