广州化学2024,Vol.49Issue(4):47-51,5.DOI:10.16560/j.cnki.gzhx.20240413
Pd@PdNi-Ti-EG纳米催化剂的制备及催化Suzuki-Miyaura反应
Synthesis of Pd@PdNi-Ti-EG Nano-catalyst and High Catalytic Performance in Suzuki-Miyaura Reaction
摘要
Abstract
A new and highly dispersed Pd@PdNi-Ti-EG heterogeneous nano-catalyst was conveniently prepared via a simple procedure.The obtained Pd@PdNi-Ti-EG nano-particle was well characterized by several physicochemical techniques,such as XRD,SEM,TEM,XPS,ICP and so on.Subsquently,this Pd@PdNi-Ti-EG nano-particle was served as the catalyst of Suzuki-Miyaura cross-coupling reaction.It was found that,with environmentally friendly ethanol/water as the reaction solvent,this catalyst showed excellent catalytic activity and functional group compatibility.Moreover,this nano-catalyst exhibited excellent recyclability that up to 15 recyclings showed no significant reduction in catalytic activity.关键词
非均相催化/纳米钯/Suzuki-Miyaura偶联反应/MOF/过渡金属催化Key words
heterogeneous catalyst/nanopalladium/Suzuki-Miyaura coupling reaction/MOF/transition-metal catalysis分类
化学化工引用本文复制引用
梁鹏飞,戴维清,范宇轩,宋娟..Pd@PdNi-Ti-EG纳米催化剂的制备及催化Suzuki-Miyaura反应[J].广州化学,2024,49(4):47-51,5.基金项目
南京邮电大学国自基金孵化项目(NY219058) (NY219058)
南京邮电大学大学生创新训练计划项目 ()