基于多组分共浸渍策略的防火木材复合材料OA
Highly Fire-resistant Wood Composites with Multi-component Co-impregnation Strategy
通过磷酸胍(GB)和硼酸(BA)两种阻燃剂共浸渍技术处理,制备了防火杂化木材,并评估了其热稳定性和防火性能.结果表明:浸渍过的木材具有更好的热稳定性,800℃下磷酸胍浸渍木材(Wood-GP)的残炭率增加至 26%,磷酸胍和硼酸共浸渍的木材(Wood-GP/BA)残炭达到 35%;此外,磷酸胍和硼酸共浸渍木材表现出优异的阻燃性,其峰值热释放速率(PHRR)和总热释放(THR)分别为 9.0 kW/m2 和 1.2 MJ/m2,与原木材相比,分别减少了 89.7%和 81.5%;炭层照片显示磷酸胍和硼酸浸渍改变了木材在燃烧过程中的热分解途径,使木材形成均匀而致密的炭层,有效阻止了热量和氧气对木材的侵蚀,大大提高了木材的阻燃和热稳定性能.
Fire-retardant wood composites were prepared by impregnation treatment with multi-component fire retardants(guanidine phosphate(GP)and boric acid(BA))and evaluated for their thermal stability and fire performance.The results showed that the impregnated wood with GP had better thermal stability,and the residual char yield increased to 26%for Wood-GP and reached 35%for Wood-GP/BA at 800℃.In addition,Wood-GP/BA exhibited excellent flame retardancy with peak heat release rate(PHRR)and total heat release(THR)of 9.0 kW/m2 and 1.2 MJ/m2,respectively,which were reduced by 89.7%and 81.5%,respectively,compared with the original wood.The guanidine phosphate and boric acid impregnation changed the thermal decomposition pathway of the wood substrate in the burning process,which led to the formation of a uniform and dense residual char layer,effectively preventing the transfer of heat and oxygen to the underlying wood,and greatly improving the flame retardancy of the wood.
李同兵;邵文龙;刘悦;叶勇强;肖飞
广东安拓普聚合物科技股份有限公司,广东 东莞 523125武汉理工大学 安全科学与应急管理学院,湖北 武汉 430070
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木材磷酸胍硼酸阻燃浸渍
woodguanidine phosphateboric acidflame retardantimpregnation
《广州化学》 2024 (004)
66-70 / 5
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