煤炭与化工2024，Vol.47Issue(8)：155-160,6.DOI:10.19286/j.cnki.cci.2024.08.035
甲醇制乙酸工艺中降低杂质离子浓度的研究进展
Progress in reducing the concentration of impurity ions in the methanol to acetic acid process
摘要
Abstract
Acetic acid is a key raw material for the synthesis of organic compounds such as ethylene acetate,acetate,acetic anhydride and chloroacetic acid.The preparation of acetic acid by methanol carbonylation is the current mainstream process,however,trace impurity ions in the reaction solution have a significant impact on the activity and stability of the catalyst.The sources of impurity ions and their negative impact on catalyst performance were analyzed using the current mainstream Cativa process(iridium-based homogeneous catalytic system)as an example.The currently adopted impurity ion treatment strategies and highlights the application of ion exchange resin technology in impurity ion removal were reviewed.Some references for the normal production of acetic acid prepared by methanol carbonylation were provided.关键词
乙酸/甲醇/羰基化/杂质金属/铱一碘催化剂/树脂脱除法Key words
acetic acid/methanol/carbonylation/impurity metals/iridium-iodine catalyst/resin removal method分类
化学化工引用本文复制引用
张宏喜,于晨雨,周美边,杨显德,顾明兰,杨晶..甲醇制乙酸工艺中降低杂质离子浓度的研究进展[J].煤炭与化工,2024,47(8):155-160,6.基金项目
广西科技重大专项(任务书编号:桂科AA23062019) （任务书编号:桂科AA23062019）
