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天然鳞片石墨球形尾料制备柔性电热膜

徐冰 杨晓蓉 刘月华 何峰 周兴 王志 公旭中

化工进展2024,Vol.43Issue(8):4534-4541,8.
化工进展2024,Vol.43Issue(8):4534-4541,8.DOI:10.16085/j.issn.1000-6613.2023-1062

天然鳞片石墨球形尾料制备柔性电热膜

Preparation of flexible electrothermal film by natural flake graphite spherical tail material

徐冰 1杨晓蓉 2刘月华 3何峰 4周兴 5王志 6公旭中7

作者信息

  • 1. 山西农业大学园艺学院,山西 晋中 030801||中国科学院过程工程研究所,北京 100190
  • 2. 中国地质大学材料科学与工程学院,北京 100083
  • 3. 中国科学院过程工程研究所,北京 100190||太原理工大学化学工程与技术学院,山西 太原 030024
  • 4. 北京服装学院材料设计与工程学院,北京 100105
  • 5. 河北师范大学中燃工学院,河北 石家庄 050024
  • 6. 中国科学院过程工程研究所,北京 100190
  • 7. 中国科学院过程工程研究所,北京 100190||中国科学院大学化工学院,北京 100049
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摘要

Abstract

With the application of spherical natural graphite in the anode material of lithium-ion battery,a large number of spherical tails are produced in the process of spheroidization of natural flake graphite,which has low utilization rate and added value.In this paper,six kinds of flexible electrothermal films were prepared by mixing spherical graphite(SG8),spherical tail and carbonylated nanocellulose in different proportions.The evolution law of electric resistance,resistivity and heating rate of electrothermal film was studied by adjusting the addition amount and voltage of spherical graphite and spherical tail.The research showed that at 10V,the resistivity of the heating film with 15%content of spherical tail was 8.57mΩ/mm reaching the maximum heating temperature of 59.3℃,and the heating rate was 0.50℃/s in the first 30s.After washing,the resistivity of the heating film with 15%content of spherical tail was 9.30mΩ/mm.The maximum heating temperature was 58.6℃,and the heating rate was 0.46℃/s in the first 30s,indicating that the spherical tail material still had good flexibility and heating properties after washing.It was proved that the natural graphite spherical tail material could be used to produce flexible electric heating materials.Compared with spherical graphite,spherical tail had better electric heating properties,which provided a solution for the high-quality utilization of natural graphite spherical tail.

关键词

球形尾料/球形天然石墨/电热膜/柔性/丝网印刷

Key words

spherical tail/spherical natural graphite/electrothermal film/flexible/screen printing

分类

机械制造

引用本文复制引用

徐冰,杨晓蓉,刘月华,何峰,周兴,王志,公旭中..天然鳞片石墨球形尾料制备柔性电热膜[J].化工进展,2024,43(8):4534-4541,8.

基金项目

国家重点研发计划(2020YFC1909605). (2020YFC1909605)

化工进展

OA北大核心CSTPCD

1000-6613

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