低碳化学与化工2024，Vol.49Issue(8)：89-99,11.DOI:10.12434/j.issn.2097-2547.20240003
二氧化碳催化加氢制高级醇催化剂研究进展
Research progress on catalysts for catalytic hydrogenation of carbon dioxide to higher alcohols
摘要
Abstract
Catalytic hydrogenation of carbon dioxide(CO2)to higher alcohols is one of the important ways to realize the high value utilization of CO2 and mitigate the greenhouse effect.The research progress on catalytic hydrogenation of CO2 to higher alcohols in recent years was reviewed.Firstly,the favorable reaction conditions and catalyst requirements for catalytic hydrogenation of CO2 to higher alcohols were analyzed from the thermodynamic point of view.Then the researches of different types of catalysts(precious metal based,copper based,cobalt and molybdenum based catalysts)applicable to the field were introduced.Finally,based on the key intermediates and main reaction pathways,the synthesis mechanisms of catalytic hydrogenation of CO2 to higher alcohols were summarized.Through summary and analysis,the main challenges in the research of catalytic hydrogenation of CO2 to higher alcohols were pointed out,and the future research direction in the field was prospected.关键词
二氧化碳/催化加氢/高级醇/催化剂/合成机理Key words
carbon dioxide/catalytic hydrogenation/higher alcohols/catalysts/synthesis mechanisms分类
化学工程引用本文复制引用
吴彬,姚如伟,牛琴琴,李聪明..二氧化碳催化加氢制高级醇催化剂研究进展[J].低碳化学与化工,2024,49(8):89-99,11.基金项目
国家自然科学基金(22202150) （22202150）
山西省重点研发计划(202202090301013) （202202090301013）
山西省自然科学基金(20210302123143). （20210302123143）
