基于微纳结构设计的电磁性能调控研究进展OA北大核心CSTPCD
Research Progress on Modulation of Electromagnetic Performance through Micro-nanostructure Design
吸波材料通过吸收电磁波能量,减少或消除电磁波的反射,从而有效降低电磁波的干扰.材料的电磁参数决定其电磁波吸收性能,调整填充比例、改变宏观形态以及复合方式等传统的调控策略存在一定局限性,无法根本改变电磁参数,阻碍了吸波材料的进一步发展.微纳结构设计策略可以改变材料的电导率、电荷密度以及磁性等理化性质,进而根本性改变材料的电磁参数,在调控电磁波吸收能力上展现出巨大优势.由于精确设计微纳结构材料难度较大且批量生产较为困难,其发展受到限制.此外,确定微纳结构与电磁波响应和损失机制之间的结构-性质理论关系仍然是一个重大的挑战.基于此,本文分析了微纳结构与电磁性能的构效关系,阐明了微纳结构设计策略在调控电磁波吸收能力方面的绝对优势,并且梳理了元素掺杂设计、表面效应调控以及成核生长控制等微纳结构改变对电磁响应机制和损耗机制的影响,为研究者们提供了基于微纳结构调控电磁性能的策略和理论指导.最后,以量子点、纳米晶以及纳米线等典型微纳米材料作为范例,综述了其调控电磁参数的策略、优势以及在电磁波吸波领域的研究现状与应用前景,为微纳米材料在电磁波吸波领域的发展提供了理论基础和策略支撑.
Absorptive materials,by absorbing electromagnetic wave energy,effectively mitigate electromagnetic interference through reduction or elimination of wave reflection.The electromagnetic parameters of materials determine their electromagnetic wave absorption performance.Traditional control strategies,such as adjusting filler ratio,changing macroscopic morphology,and regulating composite methods,have certain limitations to control their structure and cannot fundamentally alter their electromagnetic parameters,which severely hinders their further development.Now,micro-nanostructure design strategies can basically change electromagnetic parameters of the materials by altering their electrical conductivity,charge density and magnetic properties,showing significant advantages in controlling electromagnetic wave absorption capacity.However,the precise micro-nanostructure design and the mass production still face challenges to be overcome.Additionally,structure-property relationship between micro-nanostructures and electromagnetic wave response,and its underline mechanisms are still not fully understood.Herein,a comprehensive review on these relationships was introduced to elucidate the advantages of micro-nanostructure design strategies for regulating electromagnetic wave absorption capacity.Moreover,by introducing these strategies,such as element doping,surface effect modulation and nucleation-controlled growth,this review provides researchers with deep insights and theoretical guidance for modulating electromagnetic properties through micro-nanostructure design.Finally,the research progresses on electromagnetic performance modulation through micro-nanostructure design based on the case of quantum dots,nanocrystals and nanowires,as well as the current research status and prospects in the field of electromagnetic absorption were summarized,providing a theoretical foundation and strategic support for the development of micro-nanoparticles.
黄洁;汪刘应;王滨;刘顾;王伟超;葛超群
火箭军工程大学 智剑实验室,西安 710025
电磁性能微纳结构吸波机理电磁参数综述
electromagnetic performancemicro-nanostructurewave absorption mechanismelectromagnetic parameterreview
《无机材料学报》 2024 (008)
853-870 / 18
陕西省自然科学基础研究计划(2022JQ-356);中国博士后科学基金(2022M723884);陕西省高层次人才特支计划(2020-44)Natural Science Basic Research Program of Shaanxi(2022JQ-356);China Postdoctoral Science Foundation(2022M 723884);Special Support Program for High-level Talents of Shaanxi Province(2020-44)
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