管状C/SiC复合材料高温空气氧化行为与宏细观建模研究OA北大核心CSTPCD
Oxidation Behavior and Meso-macro Model of Tubular C/SiC Composites in High-temperature Environment
氧化损伤是影响火箭发动机用C/SiC复合材料喷管寿命的主要因素之一.为准确评估C/SiC复合材料喷管的氧化损伤,本研究以近似喷管结构的管状 C/SiC 复合材料为实验对象,研究了管状 C/SiC 复合材料在高温(900~1300℃)空气环境下的氧化行为,包括其组成、结构及力学性能的演变规律,发现管状C/SiC复合材料在该高温空气环境下表现出受扩散控制的氧化特征,质量与剩余强度随时间呈幂函数下降趋势,下降速率与温度正相关.在此基础上,从氧化动力学与传质学理论角度出发,建立了管状C/SiC复合材料细观/宏观尺度氧化模型,模拟了管状 C/SiC 复合材料高温空气氧化过程,并预测了材料的质量与剩余强度.模型预测结果与实验数据拟合程度较高,可为C/SiC复合材料喷管的寿命评估提供参考.
Oxidation damage is one of the main factors affecting the life of C/SiC composite nozzle used in rocket engines.To accurately predict the oxidation damage of C/SiC composite nozzle,we explored the oxidation behavior of the tubular C/SiC composites which had a similar shape to nozzle.Evolution of their composition,structure,and mechanical properties was investigated at different temperatures ranging from 900 to 1300℃.The results showed that the tubular C/SiC composites exhibited diffusion-controlled oxidation characteristics under the high-temperature environment.Their mass and residual strength decreased as a power function with time,and decline rate was positively correlated with temperature.Moreover,based on the theory of oxidation kinetics and mass transfer,a macro-meso oxidation model was established to simulate the oxidation process of tubular C/SiC composites in high-temperature environment to timely predict the evolution of their mass and residual strength.Consequentely,all the predicted results of the model fitted well with the experimental data.Our investigation consolidate that this macro-meso oxidation model is powerfull to predict the oxidation behavior and the life-span of C/SiC composite nozzle.
全文心;余艺平;方冰;李伟;王松
国防科技大学 空天科学学院,新型陶瓷纤维及其复合材料重点实验室,长沙 410073
C/SiC复合材料高温氧化氧化模型寿命预测
C/SiC compositehigh-temperature oxidationoxidation modellife prediction
《无机材料学报》 2024 (008)
920-928 / 9
湖南省自然科学基金面上项目(2023JJ30634);国家重点实验室基金(6142907230202) Natural Science Foundation of Hunan Province(2023JJ30634);State Key Laboratory Program(6142907230202)
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