中药材2024，Vol.47Issue(2)：352-356,5.DOI:10.13863/j.issn1001-4454.2024.02.015
红花中芳香苷类化学成分研究
Chemical Constituents of Aromatic Glycosides from Carthamus tinctorius
摘要
Abstract
Objective:To study the chemical constituents of Carthamus tinctorius.Methods:The chemical constituents from 70％acetone extract of Carthamus tinctorius were isolated and purified by silica,MCI gel CHP-20,Sephadex LH-20,Toyopearl HW-40C and semi-preparative HPLC.The structures were identified by physicochemical characteristics and spectroscopic data.Results:Thirteen aro-matic glycosides were isolated from Carthamus tinctorius and identified as benzyl-β-D-glucoside(1),benzyl-O-rutinoside(2),phenyle-thanol rutinoside(3),methyl 3-(4-O-β-D-glucopyranosylphenyl)propionate(4),carthamoside B5(5),junipediol A-8-O-β-D-glucopyr-anoside(6),7-O-β-benzoylrutinoside(7),syringin(8),4-allyl-2,6-dimethoxyphenyl glucoside(9),2,6-dimethoxy-4[(1E)-prop-2-enyl]phenyl-O-α-L-rhamnopyranosyl-(1→6)-β-D-glucopyranoside(10),4-O-β-D-glucopyranosyl transphenyl acrylic acid(11),4-O-β-D-glucopyranosyl cisphenyl acrylic acid(12),1-(4-O-β-D-glucopyranoside)benzoic acid(13),4-(2-aminoethyl)phenyl-1-O-β-D-glu-copyranoside(14),(+)-lyoniresinol-3α-O-β-D-glucopyranoside(15),respectively.Conclusion:Among them,compounds 1 to 4,10,13 to 15 are isolated from Carthamus genus for the first time.关键词
红花/化学成分/芳香苷类化合物Key words
Carthamus tinctorius L./Chemical constituents/Aromatic glycosides分类
中医学引用本文复制引用
马新毅,王梦娜,曹彦刚,刘晏灵,李向达,郑晓珂,冯卫生..红花中芳香苷类化学成分研究[J].中药材,2024,47(2):352-356,5.基金项目
2016年中央引导地方科技发展专项1项(豫财科[2016]149号) （豫财科[2016]149号）
河南省高层次人才特殊支持计划"千人计划"一中原领军人才(ZYQR201810080) （ZYQR201810080）
