电化学（中英文）2024，Vol.30Issue(8)：1-16,16.DOI:10.61558/2993-074X.3466
锂氧电池中钌基电催化剂的研究进展
Recent Advances on Ruthenium-based Electrocatalysts for Lithium-oxygen Batteries
摘要
Abstract
Rechargeable lithium-oxygen(Li-O2)batteries have attracted wide attention due to their high energy density.However,the sluggish cathode kinetics results in high overvoltage and poor cycling performance.Ruthenium(Ru)-based elec-trocatalysts have been demonstrated to be promising cathode catalysts to promote oxygen evolution reaction(OER).It facilitates decomposition of lithium peroxide(Li2O2)by adjusting Li2O2 morphologies,which is due to the strong interaction between Ru-based catalyst and superoxide anion(O2-)intermediate.In this review,the design strategies of Ru-based electrocatalysts are introduced to enhance their OER catalytic kinetics in Li-O2 batteries.Different configu-rations of Ru-based catalysts,including metal particles(Ru metal and alloys),single-atom catalysts,and Ru-loaded compounds with various substrates(carbon materials,metal oxides/sulfides),have been summarized to regulate the electronic structure and the matrix architecture of the Ru-based electrocatalysts.The structure-property relationship of Ru-based catalysts is discussed for a better understanding of the Li2O2 decomposition mechanism at the cathode interface.Finally,the challenges of Ru-based electrocatalysts are proposed for the future development of Li-O2 batteries.关键词
锂-氧电池/钌基电催化剂/反应机理/反应速率/过电压Key words
Lithium-oxygen battery/Ruthenium-based electrocatalyst/Reaction mechanism/Reaction kinetics/Overvoltage引用本文复制引用
王昱喆,蒋卓良,温波,黄耀辉,李福军..锂氧电池中钌基电催化剂的研究进展[J].电化学（中英文）,2024,30(8):1-16,16.基金项目
We are grateful for financial support from the National Natural Science Foundation of China(22325902 and 51671107)and Haihe Laboratory of Sustainable Chemical Transformations. （22325902 and 51671107）
