不同变质程度煤氧化特征指标量化分析OA北大核心CSTPCD

In order to study the changes of oxidation characteristics of coal with different degrees of metamorphism,the oxidation process of non-sticky coal(BN),gas-fat coal(QF)and 1/3 coking coal(1/3JM)was tested and analyzed by temperature programmed experiment system,the apparent activation energy of different oxidation stages was determined,and the change characteristics of spontaneous combustion limit parameters of coal were quantitatively calculated.The results show that the apparent activation energy of coal with low metamorphism is lower than that of coal with high metamorphism.The average apparent activation energy of BN,QF and 1/3JM coal samples is 39.90,65.28 and 69.43 kJ/mol,respectively.The apparent activation energy of coal is positively cor-related with its metamorphism,and the spontaneous combustion risk of coal with low metamorphism is higher;the apparent activa-tion energy of the same coal at different stages is also different.The apparent activation energy of BN,QF and 1/3JM coal samples at stage 1 is 55.28,75.05 and 80.79 kJ/mol,respectively,and that of stage 3 is 23.23,59.07 and 61.50 kJ/mol,respectively,which de-creases with the depth of oxidation reaction;the extreme temperature points of the three coal spontaneous combustion limit paramet-ers are 50.3,61.5 and 59.7℃,respectively.The extreme point temperatures of low-metamorphic coals are lower than those of high-metamorphic coals;under the same conditions,the minimum floating coal thickness and lower oxygen volume fraction of low meta-morphism coal are smaller,the upper air leakage intensity is larger,and the spontaneous combustion is more likely to occur.