化工进展2024，Vol.43Issue(9)：4925-4940,16.DOI:10.16085/j.issn.1000-6613.2023-1294
多孔离子聚合物催化二氧化碳环加成反应的研究进展
Research progress on CO2 cycloaddition reaction catalyzed by porous ionic polymers
摘要
Abstract
Carbon dioxide(CO2)is an abundant C1 resource,and the resource utilization of CO2 is one of the hotspots in current research.Porous ionic polymers(PIPs)combine the advantages of porous polymers and ionic liquids,showing great potential in CO2 adsorption and conversion.Based on the synthesis methods,structural properties and catalytic activity of PIPs,the recent application of porous ionic polymer catalysts such as polyionic liquids(free radical polymerization),hyper-crosslinked ionic polymers and MOFs-based ionic polymers in CO2 cycloaddition reaction is systematically reviewed.The advantages and disadvantages of preparation method and structural characteristics of various PIPs catalysts are summarized.And the structure-activity relationship and catalytic mechanism of PIPs in CO2 cycloaddition reaction are investigated.Finally,the application prospects of CO2 cycloaddition catalyzed by PIPs are prospected,including improving the catalytic activity,stability and application range of PIPs and reducing the cost.关键词
多孔聚合物/离子液体/催化剂/多相反应/二氧化碳Key words
porous polymers/ionic liquids/catalyst/multiphase reaction/carbon dioxide分类
化学化工引用本文复制引用
廖旭,周骏,罗杰,曾瑞琳,王泽宇,李尊华,林金清..多孔离子聚合物催化二氧化碳环加成反应的研究进展[J].化工进展,2024,43(9):4925-4940,16.基金项目
国家自然科学基金(21246008,21803021) （21246008,21803021）
福建省自然科学基金(2020J01065) （2020J01065）
湖南省自然科学基金(2023JJ40298) （2023JJ40298）
湖南省应用特色学科建设项目. （）
