能源环境保护2024，Vol.38Issue(5)：147-156,10.DOI:10.20078/j.eep.20240711
三乙烯四胺循环浸出废铅膏中硫酸铅的性能研究
Study on the cyclic leaching performance of lead sulfate from waste lead paste by triethylene tetramine
摘要
Abstract
The recycling of waste lead paste is the focus of the lead recycling industry.Traditional fire smelting has issues with high energy consumption and heavy pollution.Wet conversion is a green and low-carbon recycling technology for waste lead paste,but its leaching efficiency and recycling of leac-hing agent need further improvement.In this study,triethylenetetramine(TETA)was used as a leac-hing agent to investigate the cyclic leaching of PbSO4 from waste lead paste.An effective leaching model was established using the response surface method,and the leaching reaction parameters were optimized.With a n(TETA/PbSO4)ratio of 1.3,a reaction time of 11 minutes,a liquid-solid ratio of 2,and a reaction temperature of 30℃,the predicted leaching rate of PbSO4 was 99.99％,achieving an actual leaching rate of 99.93％.The apparent activation energy of PbSO4 leaching reaction was found to be 47.5 kJ/mol.Furthermore,high-purity PbCO3 with an impurity content of 0.020 4％could be ob-tained from TETA-Pb solution by using Na2CO3.This process allows for the regeneration cycle of TETA while maintaining a leaching rate of PbSO4 above 90％in 10 cycles.The results provide a reference for the high-value utilization of waste lead paste.关键词
废铅膏/湿法转化/硫酸铅/三乙烯四胺/浸出Key words
Waste lead paste/Wet conversion/Lead sulfate/Triethylenetetramine/Leaching分类
资源环境引用本文复制引用
陈彪,黄明,曹靖,张俊丰..三乙烯四胺循环浸出废铅膏中硫酸铅的性能研究[J].能源环境保护,2024,38(5):147-156,10.基金项目
国家自然科学基金面上资助项目(52070159) （52070159）
郴州国家可持续发展议程创新示范区建设专项(2022sfq25) （2022sfq25）
