中国甜菜糖业Issue(3):16-23,8.DOI:10.3969/j.issn.1002-0551.2024.03.003
葡萄糖/水溶液体系结构中红外光谱研究
Mid Infrared Spectroscopy Study on the Solution Structure of Glucose/water System
杜林楠 1吉一帆 1李穆婵 1柴嘉欣 1刘诗琪 1于宏伟2
作者信息
- 1. 石家庄学院 化工学院,河北 石家庄 050035
- 2. 石家庄学院 化工学院,河北 石家庄 050035||河北省麻醉药技术创新中心,河北 石家庄 050035
- 折叠
摘要
Abstract
The structure of glucose/water solution system was studied using mid infrared(MIR)spectroscopy.The infrared absorption modes of the main functional groups of glucose/water solution system include water mole-cule associative O-H functional group vibration mode(νO-H-associative-water),glucose molecule CH2 functional group asymmetric stretching vibration mode(νasCH2),water molecule O-H functional group bending vibration mode(δO-H-water),coupled with of CH2 functional group bending vibration and several bending vibration of func-tional groups such as OCH,CCH,COH etc(δCH2+δOCH+δCCH+δCOH),C-O functional groups in COH struc-ture stretching vibration mode(νC-O-COH),C-O functional group on sugar ring structure stretching vibration mode(νC-O-sugar ring),OCH functional group bending vibration(δOCH),C-O-H functional group bending vi-bration(δC-O-H),C-C-H functional group and O-C-H functional group bending vibration(δC-C-H+δO-C-H).As the glucose content increases in the glucose/water solution system,the hydrogen bonding between water molecules is further enhanced.This study expands the scope of MIR spectroscopy technology in the study of glucose/aqueous solution system structures and has important application value.关键词
葡萄糖/水/中红外光谱/氢键作用Key words
Glucose/Water/Mid infrared spectroscopy/Hydrogen-bonding interaction分类
物理学引用本文复制引用
杜林楠,吉一帆,李穆婵,柴嘉欣,刘诗琪,于宏伟..葡萄糖/水溶液体系结构中红外光谱研究[J].中国甜菜糖业,2024,(3):16-23,8.