大学化学2024，Vol.39Issue(8)：174-183,10.DOI:10.3866/PKU.DXHX202311051
"钴"胆英雄,根除"镍"障
Cobalt's Valor,Nickel's Foe:A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal
摘要
Abstract
Nickel,prevalently utilized in sectors such as new energy vehicle batteries and electroplating,has brought the environmental challenges,especially in the context of the national dual carbon strategy.The treatment of nickel (Ni2+)-enriched wastewater generated by these industries is pivotal for environmental conservation.Traditional Ni2+-enriched wastewater treatments,including,ion exchange resins,chemical precipitation,and fluidized bed crystallization granulation technology,often suffer from poor selectivity and the risk of secondary pollution.This study introduces an innovative approach employing a cobalt-based imidazole framework material,ZIF-67,which interacts with Ni2+to form the nickel-cobalt layered double hydroxides (NiCo-LDH),effectively enhancing Ni2+removal.The experiment spans material preparation,characterization,and adsorption performance assessment,supplemented by model analysis and mechanistic investigation.This multifaced approach aims not only to elucidate the adsorption mechanism but also to cultivate students'research interest,innovative thinking,and practical skills.Tailored for an 8-hour undergraduate comprehensive chemistry laboratory session,this experiment enables students to grasp fundamental principles and analytical methods for Ni2+removal from wastewater.It also solidifies their foundational knowledge,demonstrating the practical application of theoretical concepts in industrial settings.This experiment is designed to bolster students'comprehensive abilities,enhance their scientific literacy,and foster their innovative spirits.关键词
咪唑酯骨架材料/镍离子/吸附/综合化学实验Key words
Imidazolate framework materials/Nickel ion/Adsorption/Comprehensive chemical experiment分类
社会科学引用本文复制引用
黄光,李磊,张丁逸,王幸泽,黄余改,梁文慧,郭志芬,矫文美.."钴"胆英雄,根除"镍"障[J].大学化学,2024,39(8):174-183,10.基金项目
江苏省高等学校自然科学基金(21KJB530006) （21KJB530006）
国家自然科学基金(82173571) （82173571）
江苏第二师范学院教学改革项目(JSSNUJXGG2023QN04,JSSNUJXGG2023YB11) （JSSNUJXGG2023QN04,JSSNUJXGG2023YB11）
