广西师范大学学报（自然科学版）2024，Vol.42Issue(5)：28-38,11.DOI:10.16088/j.issn.1001-6600.2024040202
金属有机骨架基催化剂在糠醛选择性加氢反应中的应用研究进展
Recent Advances on Metal-Organic Framework-Based Catalysts for Selective Furfural Hydrogenation
摘要
Abstract
Furfural as an important biomass-derived platform molecule can be selectively hydrogenated over aldehyde group into other chemicals under the assistance of catalysts.Metal-organic framework(MOF)is a kind of crystalline porous material with periodic networks assembled by metal centers/clusters and ligands,which is often used as carrier and sources or directly used as catalyst for furfural hydrogenation with high performance.This paper summarizes design principle of MOF-based catalysts and research progress in selective furfural hydrogenation,and the critical factors and mechanisms for the reactions are analyzed.Challenges for MOF-based catalysts in hydrogenation are also analyzed and the effective acidic site regulation is a key issue,providing a reference for future synthesis of MOF-based catalysts and their furfural hydrogenation applications.关键词
糠醛/金属有机骨架/催化剂/生物质/加氢Key words
furfural/metal-organic frameworks/catalysts/biomass/hydrogenation分类
化学化工引用本文复制引用
左钧元,李欣彤,曾子涵,梁超,蔡进军..金属有机骨架基催化剂在糠醛选择性加氢反应中的应用研究进展[J].广西师范大学学报（自然科学版）,2024,42(5):28-38,11.基金项目
湖南省自然科学基金(2023JJ30573) （2023JJ30573）
湖南省大学生创新训练项目(S202310530106) （S202310530106）
