华侨大学学报（自然科学版）2024，Vol.45Issue(5)：603-609,7.DOI:10.11830/ISSN.1000-5013.202406020
一例钙金属-有机骨架的合成及其结构与性质分析
Preparation and Evaluation of Astaxanthin Composite Nanoparticles Pickering Emulsion
摘要
Abstract
A calcium metal-organic framework[Ca2(CH3COO)3(HCOO)]was obtained by solvothermal syn-thesis method,in which the formic acid ligand was generated by in-situ decomposition of the solvent N,N-dimethylformamide.The crystal structure and properties of[Ca2(CH3COO)3(HCOO)]were analyzed and characterized using X-ray single-crystal diffraction,Fourier transform infrared spectroscopy,thermogravimetric analysis and fluorescence spectrophotometry.The results show that the compound belongs to the triclinic crys-tal system with p1 space group,the unit cell parameters are a=0.671 86(6)nm,b=0.975 79(7)nm,c=0.984 60(9)nm,V=0.563 05(9)nm3,and Z=1.Ca(Ⅱ)ions(octacoordinate)form one-dimensional chains by sharing carboxyl oxygen on acetic acid,and the two sides of the chain are sandwiched by carboxyl oxygen coordinating with Ca(Ⅱ)ions(heptacoordinate)to form sandwich layers.Each sandwich layer repeatedly co-ordinates with acetic acid ligands to form two-dimensional layers,and the two carboxyl oxygen groups of for-mic acid ligands are connected to Ca(Ⅱ)ions in the two coordination modes of the layers to form a three-di-mensional organic skeleton.This compound has good stability and green light can be observed under ultraviolet light.关键词
钙金属-有机骨架/溶剂热合成法/晶体结构/荧光性质Key words
Ca metal-organic frameworks/solvothermal synthesis method/crystal structure/fluorescence分类
化学化工引用本文复制引用
王伟娟,黄丽丽,林知秋,卢冬飞,史荣会,刘耀,洪俊明..一例钙金属-有机骨架的合成及其结构与性质分析[J].华侨大学学报（自然科学版）,2024,45(5):603-609,7.基金项目
国家自然科学基金资助项目(21901040) （21901040）
福建省自然科学基金资助项目(2023J01931) （2023J01931）
华侨大学校级实验教学改革与管理课题(SY2023J08) （SY2023J08）
