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煤气化细渣残炭与煤的掺烧及其气体释放特性

折成林 白永辉 于广锁 刘夏青 马利 方鹏程 李芳

宁夏大学学报(自然科学版)2024,Vol.45Issue(3):282-289,8.
宁夏大学学报(自然科学版)2024,Vol.45Issue(3):282-289,8.

煤气化细渣残炭与煤的掺烧及其气体释放特性

Co-combustion Characteristic and Gas Emission Characteristic of Entrained Flow Gasification Fine Slag Residual Carbon and Coal

折成林 1白永辉 2于广锁 3刘夏青 1马利 1方鹏程 1李芳1

作者信息

  • 1. 国家能源集团 宁夏煤业有限责任公司煤制油化工公用设施管理分公司,宁夏 银川 750021
  • 2. 宁夏大学 化学化工学院,宁夏 银川 750021
  • 3. 宁夏大学 化学化工学院,宁夏 银川 750021||华东理工大学 资源与环境工程学院,上海 200237
  • 折叠

摘要

Abstract

In order to utilize the large amount of accumulated solid waste coal gasification fine slag(FS)in a resourceful and large-scale manner,this study uses froth flotation to enrich the residual carbon(RC)in FS.The characteristics of RC combustion alone and its co-combustion with bituminous coal are investigated using a thermogravimetric analyzer.By comparing experimental results with kinetic calculations,the ignition perfor-mance,burnout performance,combustion stability,and comprehensive combustion characteristics of particles during single and co-combustion processes are elucidated.Additionally,the emission patterns of CO,CO2,and NO2 during the combustion of RC alone and in combination with coal are explored using a mass spectrometer.The results show that the flotation process effectively reduces the aluminosilicate polymerization degree in FS,enriching RC.The addition of bituminous coal significantly enhances the combustion reactivity of RC during co-combustion.Different mass ratios of RC can effectively reduce pollutant emissions during the combustion of bituminous coal,with an 80% RC mass fraction resulting in the lowest NO2 emissions.

关键词

煤气化细渣/泡沫浮选/共燃烧特性/气体释放

Key words

fine slag/froth flotation/co-combustion characteristics/gas release

分类

化学化工

引用本文复制引用

折成林,白永辉,于广锁,刘夏青,马利,方鹏程,李芳..煤气化细渣残炭与煤的掺烧及其气体释放特性[J].宁夏大学学报(自然科学版),2024,45(3):282-289,8.

基金项目

国家自然科学基金资助项目(22168032) (22168032)

宁东能源化工基地重点基金资助项目(2023NDKJXMLX022) (2023NDKJXMLX022)

宁夏大学学报(自然科学版)

OACSTPCD

0253-2328

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