热力发电2024，Vol.53Issue(9)：118-125,8.DOI:10.19666/j.rlfd.202405108
金属有机架构物Cu-BTC低温吸附储氢数值模拟研究
Numerical simulation of hydrogen storage by adsorption on metal-organic framework Cu-BTC at low temperature
摘要
Abstract
Hydrogen storage by physical adsorption offers significant advantages,including high safety,high hydrogen storage density,and fast hydrogen charging and discharging rates,making it a highly promising method for hydrogen storage.Among the various materials,metal-organic frameworks(MOFs)have emerged as ideal hydrogen storage materials due to their highly ordered porous structures and tunable characteristics.To investigate the influence of thermal effects during the hydrogen adsorption process on storage performance,a numerical model of hydrogen storage by adsorption is established and validated.Subsequently,the hydrogen storage properties of Cu-BTC and activated carbon AX-21 tanks are analyzed and compared.Furthermore,the hydrogen storage capacity of Cu-BTC tank at different temperatures is explored.The results indicate that,compared with AX-21,the hydrogen storage capacity at room temperature increases by 12.8%when using Cu-BTC as adsorbent.When the storage temperature is reduced to 77 K,the maximum pressure in the Cu-BTC tank decreases to 0.97 MPa,and the hydrogen storage capacity increases by 174%compared with room temperature(300 K).These findings provide valuable insights for further research on the hydrogen storage capabilities of Cu-BTC materials.关键词
储氢/吸附储氢/金属有机架构物/Cu-BTC/低温吸附Key words
hydrogen storage/hydrogen adsorption storage/metal-organic frameworks/Cu-BTC/low-temperature adsorption引用本文复制引用
席肖桐,田绅,郭璐娜,陈六彪,许成杨,徐伟宸,孙志利..金属有机架构物Cu-BTC低温吸附储氢数值模拟研究[J].热力发电,2024,53(9):118-125,8.基金项目
天津市科学技术局科技帮扶提升重大工程项目(22ZYCGSN00030) Science and Technology Assistance and Promotion Major Project of Tianjin Science and Technology Bureau(22ZYCGSN00030) （22ZYCGSN00030）
