铂修饰有机铟纳米材料对丙酮的选择性响应OA
Selective Response of Platinum Modified Organic Indium Nanochitosan Composite to Acetone
采用水热合成法分步合成了铂―有机铟(Pt/Organo-In)纳米八面体结构,并且探究了它对丙酮、三乙胺、乙醇、甲醛等气体响应性能.当主要原材料硝酸铟水合物为 0.33 g对应 2 mL 5%的氯铂酸溶液的时候是最优比例,复合材料对丙酮的响应性能是最好的.在丙酮气体浓度为 20 ppm,测试温度为260℃时,材料的响应值为3.83,响应时间为 12 s,恢复时间为21 s.材料对于丙酮气体有较好的选择性,对于 20 ppm下的其他干扰气体响应值很小或者是几乎没有,一定程度说明了气体传感材料的可靠性.通过SEM、XRD、BET、FT-IR和XPS的表征与分析,证明了铂―有机铟复合材料的成功合成,为后续研究人员探索有机铟领域提供了经验.最后,研究还设计丙酮传感报警器电路示意图,为后续商业化应用做铺垫,提供了一定的理论支持和实验经验.
In this experiment,Platinum-organic indium(Pt/Organo-In)nano-octahedral structure was synthesized by hydrothermal synthesis method with distribution and its gas response properties were investigated.The best response properties were obtained when the main raw material indium nitrate was 0.33 g corresponding to 2 mL of 5%chloroplatinic acid solution as the optimal ratio.When the concentration of acetone gas is 20 ppm and the test temperature is 260℃,the response value of the material is 3.83,the response time is 12 s,and the recovery time is 21 s.The material has a good selectivity for acetone gas,and the response value for other interfering gases under 20 ppm is very small or almost none,which explains the reliability of the gas sensing material to a certain extent.The characterization and analysis by SEM,XRD,BET,FT-IR and XPS proved the successful synthesis of the Pt-organic indium material,which provides experience for subsequent researchers to explore the field of organic indium.Finally,this study also designs the schematic circuit of acetone sensing alarm,which provides certain theoretical support and experimental experience to pave the way for subsequent commercial applications.
熊小燕;龚云鹏;胡悦;孔晨光;黄有诚;陈玉放;靳焘
中国科学院广州化学研究所,广东 广州 510650||中国科学院大学,北京 100049||中科检测技术服务(广州)股份有限公司,广东 广州 510650||中国科学院新型特种精细化学品工程实验室,广东 广州 510650||国科广化(南雄)新材料研究院有限公司,广东 南雄 512400||中科广化(重庆)新材料研究院有限公司,重庆 400714中国科学院广州化学研究所,广东 广州 510650||中国科学院大学,北京 100049||中科检测技术服务(广州)股份有限公司,广东 广州 510650中国科学院广州化学研究所,广东 广州 510650||中国科学院大学,北京 100049
化学
铂有机铟纳米材料丙酮传感器
Platinumorganic indiumnanomaterialsacetone sensor
《纤维素科学与技术》 2024 (003)
20-25 / 6
重庆市面上项目(CSTB2022NSCQ-MSX0986).
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