碳排放视角下剩余污泥作为污水脱氮碳源的可行性分析OA北大核心CSTPCD
Feasibility analysis of excess sludge as carbon source for wastewater denitrification from the perspective of carbon emissions
随着碳中和目标的提出,剩余污泥的资源化利用已经成为一个研究热点.为了从碳排放视角分析剩余污泥作为污水脱氮碳源的可行性,本研究以日处理规模为1×104m3污水为核算对象,构建了一条剩余污泥碱解液作为脱氮碳源的完整工艺路线,即剩余污泥经NaOH碱解预处理-上清液鸟粪石结晶回收磷-短程硝化耦合厌氧氨氧化脱氮-脱氮除磷后上清液作为脱氮碳源利用,对不同剩余污泥回用比情景下的碳排放量进行核算,分析该工艺的可行性.碱解上清液脱氮会消耗部分碳源,因此本文还对比研究了剩余污泥碱解液仅经磷回收后直接用于污水脱氮的工艺路线.结果表明,剩余污泥碱解液用于污水脱氮过程的碳排放量小于外加碳源情形,其运行成本也低于原污水处理工艺.理论上来讲,污泥回用比越高,全程碳排放量越小,在剩余污泥回用比为100%时,剩余污泥碱解液经磷回收后用于污水脱氮产生的碳排放最小,为0.309 6 kg·m-3,此时处理每万m3污水的运行成本较原工艺节约1 222.0~1 261.1元.但考虑到可能会有惰性物质在系统中循环累积,故实际最佳回用比还需深入研究确定.本文的研究成果表明,在污水处理过程中将剩余污泥作为脱氮碳源具有可行性.
With the increasing emphasis on carbon neutrality,the exploration of resource utilization for excess sludge has gained prominence.In order to assess the viability of utilizing excess sludge as a carbon source for nitrogen removal in sewage treatment,focusing on the perspective of carbon emissions,a daily sewage treatment volume of 10 000 m3 was taken as the basis for calculation in this study.A comprehensive process route employing excess sludge alkaline hydrolysate as a carbon source for nitrogen removal was established.The proposed process involves alkaline hydrolysis pretreatment of excess sludge with NaOH,recovery of phosphorus through supernatant struvite crystallization,nitrogen removal via partial nitrification and anammox,and utilization of the supernatant from post-nitrogen and phosphorus removal process as the carbon source for nitrogen removal.The feasibility of this process was evaluated based on the different scenarios involving various excess sludge recycle ratios for carbon emissions accounting.Considering that denitrification of alkaline hydrolysis supernatant consumes a portion of COD,the option of denitrification directly after phosphorus recovery from the excess sludge alkaline hydrolysis solution was also investigated.The results indicate that the carbon emissions from the excess sludge alkaline hydrolysis solution are lower than those from an external carbon source,with the operational cost also being less than that of the original wastewater treatment process.Theoretically speaking,the higher the sludge reuse ratio,the smaller the carbon emission in the whole process,with a 100%reuse ratio of excess sludge,the carbon emissions from the excess sludge alkaline hydrolysis solution after phosphorus recovery for wastewater denitrification could reach the lowest value of a 0.309 6 kg·m-3.During this condition,the operational cost savings of 1 222.0~1 261.1 yuan per 10 000 m3 of wastewater treatment compared to the original process.However,considering the accumulation of inert substances in the system,the actual optimal reuse ratio needs to be further studied.The results of this paper show that it is feasible to use the excess sludge as a denitrification carbon source in the sewage treatment process.
刘德兰;封莉;韩绮;高鹏;张立秋
北京林业大学环境科学与工程学院,北京 100083||北京林业大学,北京市水体污染源控制技术重点实验室,北京 100083
环境科学
剩余污泥污水脱氮碳源碳排放核算
excess sludgewastewater denitrificationcarbon sourcecarbon emission accounting
《环境工程学报》 2024 (008)
2089-2098 / 10
重点研发计划项目(2023YFC3207703);国家自然科学基金面上资助项目(41977317,42177051,52170021)
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