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酚醛-不饱和聚酯树脂石墨双极板复合材料研究

李航 杜玲枝 吴晓林 冯巧 李桂丽

中国塑料2024,Vol.38Issue(10):5-9,5.
中国塑料2024,Vol.38Issue(10):5-9,5.DOI:10.19491/j.issn.1001-9278.2024.10.002

酚醛-不饱和聚酯树脂石墨双极板复合材料研究

Study on phenolic resin/unsaturated polyester/graphite/composites for bipolar plate

李航 1杜玲枝 2吴晓林 1冯巧 3李桂丽3

作者信息

  • 1. 郑州大学化工学院,郑州 450001
  • 2. 郑州大学化工学院,郑州 450001||河南城建学院材料与化工学院,平顶山 467041
  • 3. 河南城建学院材料与化工学院,平顶山 467041
  • 折叠

摘要

Abstract

In this study,the bipolar plate composites were prepared by using a compression-molding technology using nat-ural flake graphite(NG)as conductive aggregate,phenolic resin(PF)and unsaturated polyester resin(UPR)as bind-ers.The effects of the mass ratio of PF to UPR,resin content,and molding conditions on the electrical conductivity and bending strength of the composites were studied by differential scanning calorimetry.The results indicated that the bipo-lar plate composites obtained an electrical conductivity of 336.1 S/cm and bending strength of 46.5 MPa at a resin con-tent of 20 wt%with a NG/PF/UPR mass ratio of 6∶1,a pressing temperature of 100 ºC,a molding pressure of 30 MPa,a molding temperature of 180 ºC,and a molding time of 2 h.Compared to the NG/PF bipolar plate composite under the same processing conditions,the NG/PF/UPR bipolar plate composites exhibited an increase in electrical con-ductivity by 134.9%and in bending strength by 21.2%.

关键词

天然鳞片石墨/酚醛树脂/不饱和聚酯树脂/电导率/弯曲强度

Key words

natural flake graphite/phenolic resin/unsaturated polyester resin/electrical conductivity/bending strength

分类

化学化工

引用本文复制引用

李航,杜玲枝,吴晓林,冯巧,李桂丽..酚醛-不饱和聚酯树脂石墨双极板复合材料研究[J].中国塑料,2024,38(10):5-9,5.

中国塑料

OA北大核心CSTPCD

1001-9278

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