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硅-铝包覆TiO2功能化SBS改性沥青抗老化机理及性能研究

杨喜英 张文才 曲立杰 史文秀

中国塑料2024,Vol.38Issue(10):29-35,7.
中国塑料2024,Vol.38Issue(10):29-35,7.DOI:10.19491/j.issn.1001-9278.2024.10.006

硅-铝包覆TiO2功能化SBS改性沥青抗老化机理及性能研究

Study on anti-aging mechanism and performance of asphalt modified with Si-Al coated TiO2-functionalized SBS

杨喜英 1张文才 2曲立杰 1史文秀3

作者信息

  • 1. 山西工程科技职业大学交通工程学院,山西 晋中 030619
  • 2. 山西工程科技职业大学交通工程学院,山西 晋中 030619||太原理工大学化学工程与技术学院,太原 030024
  • 3. 山西省交通建设工程质量检测中心(有限公司),太原 030006
  • 折叠

摘要

Abstract

In order to better utilize the excellent UV shielding function of nano-TiO2,improve the anti-aging performance of SBS-modified asphalt,and address a difficulty in the dispersion of nano-TiO2 in the SBS-modified asphalt system,the Si-Al coated nano-TiO2 was prepared using a Si-Al coprecipitation method to form the coating film on the surface of nano-TiO2.This approach can effectively prevent the oxidation of SBS-modified asphalt caused by nano-TiO2 due to its photo-catalytic activity and thus enhance the anti-aging performance of nano-TiO2-functionalized SBS-modified asphalt.The coating effect and morphological microstructure of the coated nano-TiO2 were investigated by TEM and XRD,the ultra-violet(UV)absorption capacity of the modified asphalt was analyzed by UV spectrophotometry,the influence of Si-Al coating on the dispersion and stability of nano-TiO2 and SBS was evaluated by SEM and fluorescence microscopy,and the anti-aging mechanism of the Si-Al coated nano-TiO2 functionalized SBS-modified asphalt was analyzed by FTIR spectroscopy.Finally,the performance of the functionalized SBS-modified asphalt was studied.The results indicated that the dispersion and stability of nano-TiO2 and SBS in asphalt were effectively improved when 6 wt%Si-Al coated na-no-TiO2 was incorporated.In this case,the oxidation effect of nano-TiO2 on the modified asphalt could be suppressed,and the anti-aging performance of the SBS-modified asphalt could be improved.

关键词

苯乙烯-丁二烯-苯乙烯嵌段共聚物改性剂/纳米二氧化钛/改性沥青/老化性能

Key words

styrenic block copolymer/nano titanium dioxide/modified asphalt/aging performance

引用本文复制引用

杨喜英,张文才,曲立杰,史文秀..硅-铝包覆TiO2功能化SBS改性沥青抗老化机理及性能研究[J].中国塑料,2024,38(10):29-35,7.

基金项目

山西交通控股集团有限公司科技项目(2022-JKKJ-33) (2022-JKKJ-33)

山西工程科技职业大学科技项目(KJ202307) (KJ202307)

中国塑料

OA北大核心CSTPCD

1001-9278

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