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蔗糖改性小桐子蛋白胶黏剂性能研究

张倩玉 陈艳华 丛郁锬 雷洪 杜官本 席雪冬

西南林业大学学报2024,Vol.44Issue(9):176-182,7.
西南林业大学学报2024,Vol.44Issue(9):176-182,7.DOI:10.11929/j.swfu.202306063

蔗糖改性小桐子蛋白胶黏剂性能研究

Study on the Performance of Sucrose Modified Jatropha curcas Protein Adhesive

张倩玉 1陈艳华 1丛郁锬 1雷洪 2杜官本 1席雪冬1

作者信息

  • 1. 西南林业大学云南省木材胶粘剂及胶合制品重点实验室,云南 昆明 650233
  • 2. 浙江农林大学化学与材料工程学院,浙江 杭州 311300
  • 折叠

摘要

Abstract

The study incorporated sucrose as a modifier to improve the bonding performance of the Jatropha curcas protein adhesive,achieved through normal temperature oxidation.Utilizing KMnO4 oxidation,the excess hydroxyl groups of sucrose in the reaction were transformed into additional aldehydes,facilitating full crosslink-ing with the protein and thus forming the J.curcas protein adhesive.Dynamic thermomechanical analysis(DMA)and Fourier transform infrared spectroscopy(FTIR)instruments were used to analyze its thermal properties and structure.The results showed that with the increase of sucrose addition,the performance of J.curcas protein ad-hesive increased first,it also showed a decrease when the amount added was too much and the best sucrose dosage is 20%,the oxidation treatment protein adhesive has higher reactivity and excellent bonding performance when KMnO4 is used as the oxidant,the additive amount is 12%,the oxidation time is 12 minutes,and the pH value is 7.Its the dry strength of plywood as high as 1.63 MPa,the 3 h 63 ℃ water soaking wet strength and 24 h cold wa-ter soaking strength were 0.84 MPa and 0.81 MPa,and that are all conformed the performance requirements of GB/T 9846-2015 for Type Ⅱ plywood.

关键词

常温氧化/小桐子饼粕粉/蔗糖/胶黏剂

Key words

normal temperature oxidation/Jatropha curcas powder/sucrose/adhesive

分类

农业科技

引用本文复制引用

张倩玉,陈艳华,丛郁锬,雷洪,杜官本,席雪冬..蔗糖改性小桐子蛋白胶黏剂性能研究[J].西南林业大学学报,2024,44(9):176-182,7.

基金项目

云南省应用基础研究项目(202201AU070222,202101BD070001-074)资助 (202201AU070222,202101BD070001-074)

云南省教育厅科学研究基金项目(2022J0490,2023Y0697)资助. (2022J0490,2023Y0697)

西南林业大学学报

OA北大核心CSTPCD

2095-1914

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