电化学（中英文）2024，Vol.30Issue(9)：1-9,9.DOI:10.61558/2993-074X.3460
氮掺杂碳纳米管上钴和钌位点之间的电子通信促进碱性析氢反应
Electronic Communication Between Co and Ru Sites Decorated on Nitrogen-Doped Carbon Nanotubes Boosting the Alkaline Hydrogen Evolution Reaction
摘要
Abstract
Designing highly efficient Pt-free electrocatalysts with low overpotential for an alkaline hydrogen evolution reaction(HER)remains a significant challenge.Here,a novel and efficient cobalt(Co),ruthenium(Ru)bimetallic electro-catalyst composed of CoRu nanoalloy decorated on the N-doped carbon nanotubes(CoRu@N-CNTs),was prepared by reacting fullerenol with melamine via hydrothermal treatment and followed by pyrolysis.Benefiting from the electronic communication between Co and Ru sites,the as-obtained CoRu@N-CNTs catalyst exhibited superior electrocatalytic HER activity.To deliver a current density of 10 mA·cm-2,it required an overpotential of merely 19 mV along with a Tafel slope of 26.19 mV·dec-1 in 1 mol·L-1 potassium hydroxide(KOH)solution,outperforming the benchmark Pt/C catalyst.The present work would pave a new way towards the design and construction of an efficient electrocatalyst for energy storage and conversion.关键词
钴钌合金/电催化剂/水裂解/析氢反应/碳纳米管Key words
CoRu alloy/Electrocatalyst/Water splitting/Hydrogen evolution reaction/Carbon nanotubes引用本文复制引用
高梦婷,黄剑锋,冯永强,卫莹,霍雪萌,朱文洁,刘箐箐,强晋源,刘婉婉,王颖,李旭..氮掺杂碳纳米管上钴和钌位点之间的电子通信促进碱性析氢反应[J].电化学（中英文）,2024,30(9):1-9,9.基金项目
This work was supported by the National Natural Science Foundation of China(No.52072226,U22A20144),Key Research and Development Pro-gram of Shaanxi(2024GX-YBXM-466),Science and Technology Program of Xi'an,China(22GXFW0013),and Science and Technology Program of Weiyang District of Xi'an,China(202315). （No.52072226,U22A20144）
