高等学校化学学报2024，Vol.45Issue(12)：104-113,10.DOI:10.7503/cjcu20240367
ZnCo-POPs球形材料衍生双金属催化剂协同催化烯烃与空气的环氧化
Synergistic Catalysis Epoxidation of Olefins and Air by Bimetallic Catalysts Derived from ZnCo-POPs Spherical Materials
摘要
Abstract
As a new type of porous material,porous organic polymers(POPs)is widely used in heterogeneous catalysis because of its unique advantages.In this paper,a series of ZnCo-POPs bimetallic catalytic materials with different compositions were prepared by impregnation method and characterized by means of X-ray diffraction(XRD),field emission scanning electron microscope(FESEM),X-ray photoelectron spectroscopy(XPS),specific surface area and pore size analysis(BET).The Zn0.3Co0.6-POP-250-2 catalyst prepared by impregnation method showed the best catalytic activity.When N,N-dimethyl formamide(DMF)was used as the reaction solvent and the reaction temperature was 90℃for 5 h,94.3%α-pinene conversion and 95.2%epoxide selectivity were obtained,and the catalytic activity of the catalyst did not decrease obviously after being recycled for 5 times,which indicated that Zn0.3Co0.6-POP-250-2 catalyst has excellent catalytic performance and good stability.关键词
多孔有机聚合物/Zn0.3Co0.6-POPs/烯烃/空气/环氧化Key words
Porous organic polymers(POPs)/Zn0.3Co0.6-POPs/Olefins/Air/Epoxidation分类
化学化工引用本文复制引用
李婷,鲁新环,李茜茜,程柔,郭昊天,占俊辉,周丹,夏清华..ZnCo-POPs球形材料衍生双金属催化剂协同催化烯烃与空气的环氧化[J].高等学校化学学报,2024,45(12):104-113,10.基金项目
国家自然科学基金(批准号:22072038,22272045)、有机功能分子合成与应用教育部重点实验室开放项目(批准号:KLSAOFM2109)和药物合成与优化湖北省重点实验室开放项目(批准号:ZD202302).Supported by the National Natural Science Foundation of China(Nos.22072038,22272045),the Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules Open Fund,China(No.KLSAOFM2109)and the Open Funding Project of Hubei Provincial Key Laboratory of Drug Synthesis and Optimization,China(No.ZD202302). （批准号:22072038,22272045）
