中国塑料2024，Vol.38Issue(11)：57-63,7.DOI:10.19491/j.issn.1001-9278.2024.11.010
基于共价自适应网络的可回收再利用阻燃双马树脂研究
Study on recyclable and reusable flame-retardant bismaleimide resin based on covalent adaptive network
黎友霜 1金秋硕 1唐璟玥 1贾梦 1许博1
作者信息
- 1. 北京工商大学轻工科学与工程学院,北京 100048
- 折叠
摘要
Abstract
In this study,DOPO-DBA-F as a flame-retardant cross-linking agent was introduced into the bismaleimide res-in as a raw material to prepare a modified material with both self-healing and flame-retardant properties.The structure and performance of the modified material was characterized by using Fourier-transform infrared spectroscopy,thermogra-vimetry analysis,differential scanning calorimetry(DSC),polarized light microscopy,limiting oxygen index meter,ver-tical burning experiment,and cone calorimetry.The morphology of the residual char was observed by scanning electron microscopy.The results indicated that the formation of reversible Diels-Alder(DA)bonds effectively improved the recy-clability of the bismaleimide resin.The presence of the reversible DA bonds between the furan groups and bismaleimide resin was confirmed by DSC.Meanwhile,the introduction of flame-retardant cross-linking agent successfully improved the flame-retardant properties of the modified material,resulting in a limiting oxygen index of 38.5％and a UL94 V-0 rating in the vertical burning experiment.关键词
双马来酰亚胺树脂/Diels-Alder反应/自愈合/阻燃Key words
bismaleimide resin/Diels-Alder reaction/self-healing/flame retardancy分类
化学化工引用本文复制引用
黎友霜,金秋硕,唐璟玥,贾梦,许博..基于共价自适应网络的可回收再利用阻燃双马树脂研究[J].中国塑料,2024,38(11):57-63,7.
