石墨掺杂刨花板低碳制备工艺及性能OA北大核心CSTPCD
Low carbon preparation process and properties of graphite doped particleboard
木材等植物原料具有较低的导热性能,在刨花板热压过程中,热传递效率较低,不利于实现"双碳"目标.引入石墨这种导热性能优异的材料,并探讨了石墨添加量(1%,3%,5%)、石墨粒径(45,11,6.5 μm)配比(1∶1∶1,0.5∶1∶1.5,1.5∶1∶0.5)以及热压温度(150,170,190 ℃)对刨花板物理力学性能和剖面密度分布的影响,探究了热压时板坯内部温度和蒸汽压力的变化.结果表明,刨花板的静曲强度、弹性模量、内结合强度和板面握钉力受石墨添加量的影响较大,而24 h吸水厚度膨胀率主要受石墨粒径配比影响.随着石墨添加量(1%~5%)的增加,刨花板的内结合强度、弹性模量、静曲强度、24 h吸水厚度膨胀率和板面握钉力呈下降趋势.当石墨粒径配比为1∶1∶1时,刨花板的吸水厚度膨胀率最小.提高热压温度可促进刨花板性能的提升,在固定石墨粒径配比(1∶1∶1)和添加量(1%)的条件下,不同热压温度下石墨的引入均能提升热压过程中板坯内部的温度和蒸汽压力,尤其是在较低热压温度下,石墨的影响更为显著.同时,石墨还可以提高刨花板的导热系数,进一步优化了热压效率.经综合考量,较佳的石墨添加工艺为石墨添加量1%、石墨粒径配比1∶1∶1和热压温度150 ℃.
Wood and other plant materials have low thermal conductivity,resulting in inefficient heat transfer during the hot-pressing process of particleboards,which hinders the achievement of the"Double carbon"goal.To address this challenge,this study introduced graphite,a material with excellent thermal conductivity,and investigated the effects of different graphite additions(1%,3%,5%),mass ratios(1∶1∶1,0.5∶1∶1.5,1.5∶1∶0.5)of graphite with different particle sizes(45,11,6.5 µm),and hot-pressing temperatures(150,170,190 ℃)on the physical and mechanical properties of particleboard and its density distribution.Changes in internal temperature and water vapor pressure of the particleboard during hot-pressing were also examined.The results showed that the bending strength,modulus of elasticity,internal bonding strength,and screw withdrawal of particleboard were significantly influenced by graphite additions,while the 24 h thickness swelling rate of particleboard was mainly affected by graphite particle size ratios.With the increase of graphite addition(l%-5%),the internal bonding strength,modulus of elasticity,bending strength,24 h thickness swelling rate,and screw withdrawal of particleboard decreased.At a graphite addition of 1%,the internal bonding strength of particleboards prepared under hot-pressing temperatures of 150,170,and 190℃ increased by 13.2%,30.4%and 9.8%,respectively,compared to the particleboard without graphite added.The minimum 24 h thickness swelling rate of particleboard was achieved with a graphite particle size ratio of 1∶1∶1.The performance of particleboard improved with increasing hot-pressing temperature,when the graphite particle size ratio and addition amount were fixed at 1∶1∶1 and 1%,the introduction of graphite increased the temperature and steam pressure inside the slab during hot-pressing at 150,170 and 190 ℃,especially at lower hot-pressing temperatures.At hot-pressing temperature of 150 ℃,the addition of graphite caused the core temperature of the slab to be higher than that of the particleboard without graphite added at a hot-pressing temperature of 170 ℃ in the first 180 s of the hot-pressing process.Meanwhile,the addition of graphite also enhanced the thermal conductivity of particleboard,further optimizing the efficiency of the hot-pressing process.Considering all factors,the optimal graphite addition process can be achieved by the addition of 1%graphite,with 1∶1∶1 graphite particle size ratio,and using hot-pressing temperature of 150 ℃.
王军锋;李玉权;龙克莹;王冠昌;汤正捷
广西壮族自治区林业科学研究院,广西林业实验室,广西木材资源培育质量控制工程技术研究中心,广西优良用材林资源培育重点实验室,南宁 530002西南林业大学材料与化学工程学院,昆明 650224
林学
石墨刨花板低碳制造导热热压工艺
graphiteparticleboardlow carbon manufacturingheat conductionhot-pressing process
《林业工程学报》 2024 (006)
52-59 / 8
广西重点研发计划项目(桂科AB23026096);广西科技重大专项课题(桂科AA23062014-1).
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