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U3O8的硝酸连续溶解试验研究

康绍辉 叶开凯 张佳宇 牛玉清 李大炳 周志全 张永明 曹令华 任燕 王皓 曹笑豪

湿法冶金2024,Vol.43Issue(6):640-645,6.
湿法冶金2024,Vol.43Issue(6):640-645,6.DOI:10.13355/j.cnki.sfyj.2024.06.007

U3O8的硝酸连续溶解试验研究

Continuous Dissolution of U3O8 in Nitric Acid

康绍辉 1叶开凯 1张佳宇 1牛玉清 1李大炳 1周志全 1张永明 1曹令华 1任燕 1王皓 1曹笑豪1

作者信息

  • 1. 核工业北京化工冶金研究院,北京 101149
  • 折叠

摘要

Abstract

In view of the"bimodal"particle size distribution phenomenon of U3O8 raw materials,the process concept of rapid dissolution of fine U3O8 and continuous dissolution of large U3O8 at the bottom of the equipment was put forward,and a tank-type continuous dissolution device was designed.The rationality of the proposed tank-type dissolution device,the feasibility of the continuous dissolution process of U3O8 in nitric acid,and its applicability to different raw materials were verified through micro,small-scale,and pilot tests.The results show that under the conditions of the nitric acid concentration of 6 mol/L,dissolution temperature of approximately 60 ℃,and residence time of 40 minutes,U3O8 from different sources can be effectively dissolved,the uranium mass concentration in the dissolution solution is 350~400 g/L.

关键词

八氧化三铀/连续溶解/硝酸/铀酰

Key words

U3O8/continuous dissolution/nitric acid/uranyl nitrate

分类

能源科技

引用本文复制引用

康绍辉,叶开凯,张佳宇,牛玉清,李大炳,周志全,张永明,曹令华,任燕,王皓,曹笑豪..U3O8的硝酸连续溶解试验研究[J].湿法冶金,2024,43(6):640-645,6.

基金项目

国家自然科学基金资助项目(U2267225) (U2267225)

国家重点研发计划项目(2023YFC2907802) (2023YFC2907802)

中核集团领创科研项目(CNNC-JCYJ202211). (CNNC-JCYJ202211)

湿法冶金

OA北大核心

1009-2617

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