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高强紫外辐照对改性聚乙烯性能的影响

江猛 孙小杰 孙苗苗 李亚飞 朱鹤翔

塑料科技2024,Vol.52Issue(11):24-29,6.
塑料科技2024,Vol.52Issue(11):24-29,6.DOI:10.15925/j.cnki.issn1005-3360.2024.11.005

高强紫外辐照对改性聚乙烯性能的影响

Effect of High Intensity Ultraviolet Irradiation on Properties of Modified Polyethylene

江猛 1孙小杰 1孙苗苗 1李亚飞 1朱鹤翔1

作者信息

  • 1. 北京低碳清洁能源研究院,北京 102211
  • 折叠

摘要

Abstract

The high-dose ultraviolet(UV)aging test of high density polyethylene(HDPE)composites modified by different contents of compound light stabilizer was tested by UV aging test chamber with UV irradiation intensity of 500 W/m2.Fourier transform infrared spectroscopy(FTIR)test showed that the carbonyl index was positively correlated with the aging degree of HDPE.The aging rate of HDPE was significantly reduced by the addition of ultraviolet additives.The molecular weight of modified HDPE was analyzed by rotating rheology,which could found that the crosslinking reaction rate of HDPE was inhibited more with the increase of ultraviolet additives in the early aging period.Combined with the above analysis and mechanical test results,it was found that when the modified HDPE material needed to withstand the total ultraviolet irradiation of 200 kWh/m2,the modified HDPE material could maintain good properties by only adding 1.2 phr compound light stabilizer in 100 phr matrix.The retention rates of elongation at break,tensile strength and notch impact strength were 57.7%,63.8%and 105.0%,respectively.

关键词

高强紫外辐照/紫外辐照总量/高密度聚乙烯/复配光稳定剂

Key words

High intensity UV irradation/Total UV exposure/HDPE/Compound light stabilizer

分类

化学化工

引用本文复制引用

江猛,孙小杰,孙苗苗,李亚飞,朱鹤翔..高强紫外辐照对改性聚乙烯性能的影响[J].塑料科技,2024,52(11):24-29,6.

塑料科技

OA北大核心CSTPCD

1005-3360

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