应用化学2024，Vol.41Issue(11)：1535-1551,17.DOI:10.19894/j.issn.1000-0518.240183
微反应器内有机过氧化物合成研究进展
Research Progress on the Synthesis of Organic Peroxide in Microreactor
摘要
Abstract
Organic peroxides are widely used chemical additives as polymerization initiators,polyester curing agents,crosslinking agents for polymer materials,and oxidants.The traditional synthesis process within batch reactor has low phase transfer rate,uncontrollable process parameters,large liquid hold-up,leading to low efficiency,poor quality,and high risk.Microreaction systems have unique advantages for peroxidation process due to their large specific surface area,enhanced mass and heat transfer rates,and high controllability.This article reviews the research progress on the synthesis of organic peroxides in microreactors in the past decadefrom the perspective of the general and specific challenges lying in the synthesis of organic peroxide acid,peroxyesters,alkyl hydroperoxide,and ketone peroxide.It introduces the commonly used reaction systems,operating parameters,and microreactor types for the synthesis of organic peroxides,discusses the important role and potential problems of microreactors in improving the controllability,efficiency,and safety in peroxidation reaction.Finally,the solutions and future development trends for the improvement of peroxidation in micro-scale are proposed.关键词
有机过氧化物/连续流合成/微反应器/过程强化Key words
Organic peroxide/Continuous synthesis/Microreactor/Process intensification分类
化学化工引用本文复制引用
伊绘霖..微反应器内有机过氧化物合成研究进展[J].应用化学,2024,41(11):1535-1551,17.基金项目
国家自然科学基金(No.22278452)资助 Supported by the National Natural Science Foundation of China(No.22278452) （No.22278452）
