新型炭材料（中英文）2024，Vol.39Issue(1)：42-63,22.DOI:10.1016/S1872-5805(24)60836-X
碳基无金属纳米材料用于电催化合成小分子化学品
Carbon-based metal-free nanomaterials for the electrosynthesis of small-molecule chemicals:A review
摘要
Abstract
Electrocatalysis is a key component of many clean energy technologies that has the potential to store renewable electri-city in chemical form.Currently,noble metal-based catalysts are most widely used for improving the conversion efficiency of react-ants during the electrocatalytic process.However,drawbacks such as high cost and poor stability seriously hinder their large-scale use in this process and in sustainable energy devices.Carbon-based metal-free catalysts(CMFCs)have received growing attention due to their enormous potential for improving the catalytic performance.This review gives a concise comprehensive overview of re-cent developments in CMFCs for electrosynthesis.First,the fundamental catalytic mechanisms and design strategies of CMFCs are presented and discussed.Then,a brief overview of various electrosynthesis processes,including the synthesis of hydrogen peroxide,ammonia,chlorine,as well as various carbon-and nitrogen-based compounds is given.Finally,current challenges and prospects for CMFCs are highlighted.关键词
电合成/电催化/碳基纳米材料/无金属电催化剂/小分子化学品Key words
Electrosynthesis/Electrocatalysis/Carbon-based nanomaterials/Metal-free electrocatalysts/Small-molecule chemicals分类
通用工业技术引用本文复制引用
石磊,李彦哲,尹华杰,赵慎龙..碳基无金属纳米材料用于电催化合成小分子化学品[J].新型炭材料（中英文）,2024,39(1):42-63,22.基金项目
This work was financially supported by the Na-tional Natural Science Foundation of China(22373027,52102325). 国家自然科学基金面上项目(22373027) （22373027,52102325）
国家自然科学基金青年科学基金项目(52102325). （52102325）
