新型炭材料（中英文）2024，Vol.39Issue(1)：64-77,14.DOI:10.1016/S1872-5805(24)60829-2
炭材料在电解水制氢耦合有机氧化方面的研究进展
A review of carbon-based catalysts and catalyst supports for simultaneous organic electro-oxidation and hydrogen evolution reactions
摘要
Abstract
Producing organic electro-oxidation and hydrogen evolution reactions(HER)simultaneously in an electrolytic cell is an appealing method for generating valuable chemicals at the anode while also producing H2 at the cathode.Within this framework,the task of designing energy-saving electrocatalysts with high selectivity and stability is a considerable challenge.Carbon-based cata-lysts,along with their supports,have emerged as promising candidates due to their diverse sources,large specific surface area,high porosity and multidimensional characteristics.This review summarizes progress from 2012 to 2022,in the use of carbon-based cata-lysts and their supports for organic electrooxidation and HER.It delves into outer-sphere electrooxidation mechanisms involving mo-lecule-mediated oxidation and oxidative radical coupling reactions,as well as inner-sphere electrooxidation mechanisms,encom-passing both acidic and alkaline electrolytes.The review also explores prospective research directions within this domain,addressing various aspects such as the design of electrocatalytic materials,the study of the relationship between the structure and properties of electrocatalysts,as well as examining their potential industrial applications.关键词
炭材料/氢气/电解水/有机物氧化/电催化Key words
Carbon-based materials/Hydrogen/Electrochemical water splitting/Organic oxidation/Electrocatalysis引用本文复制引用
王治栋,夏天,栗振华,邵明飞..炭材料在电解水制氢耦合有机氧化方面的研究进展[J].新型炭材料（中英文）,2024,39(1):64-77,14.基金项目
This work was funded by the National Key R&D Program of China(2022YFB4002700),the National Natural Science Foundation of China(22108008,22090031,21991102,22288102),the Young Elite Scientist Sponsorship Program by CAST(2021QN-RC001),and the Fundamental Research Funds for the Central Universities(buctrc202011). 国家重点科技攻关计划(2022YFB4002700) （2022YFB4002700）
国家自然科学基金(22108008,22090031,21991102,22288102) （22108008,22090031,21991102,22288102）
中国科学院青年杰出科学家资助计划(2021QNRC001) （2021QNRC001）
中央高校基础科学基金(BUCTRC202011). （BUCTRC202011）
