新型炭材料（中英文）2024，Vol.39Issue(5)：872-895,24.DOI:10.1016/S1872-5805(24)60873-5
金属有机框架及其衍生物在锂离子电容器中的应用
The application of metal-organic frameworks and their derivatives for lithium-ion capacitors
赵沙沙 1张熊 2李晨 3安亚斌 2胡涛 1王凯 2孙现众 2马衍伟2
作者信息
- 1. 中国科学院电工研究所,高密度电磁动力与系统重点实验室(中国科学院),北京 100190||中国科学院大学,北京 100049
- 2. 中国科学院电工研究所,高密度电磁动力与系统重点实验室(中国科学院),北京 100190||中国科学院大学,北京 100049||齐鲁中科电工与先进电磁驱动技术研究所,山东省先进电磁转换技术重点实验室,山东济南 250013
- 3. 中国科学院电工研究所,高密度电磁动力与系统重点实验室(中国科学院),北京 100190||齐鲁中科电工与先进电磁驱动技术研究所,山东省先进电磁转换技术重点实验室,山东济南 250013
- 折叠
摘要
Abstract
There is an urgent need for lithium-ion capacitors(LICs)that have both high energy and high power densities to meet the continuously growing energy storage demands.LICs effectively balance the high energy density of traditional rechargeable bat-teries with the superior power density and long life of supercapacitors(SCs).Nevertheless,the development of LICs is still hampered by limited kinetic processes and capacity mismatch between the cathode and anode.Metal-organic frameworks(MOFs)and their de-rivatives have received significant attention because of their extensive specific surface area,different pore structures and topologies,and customizable functional sites,making them compelling candidate materials for achieving high-performance LICs.MOF-derived carbons,known for their exceptional electronic conductivity and large surface area,provide improved charge storage and rapid ion transport.MOF-derived transition metal oxides contribute to high specific capacities and improved electrochemical stability.Addi-tionally,MOF-derived metal compounds/carbons provide combined effects that increase both the capacitive and Faradaic reactions,leading to a superior overall performance.The review begins with an overview of the fundamental principles of LICs,followed by an exploration of synthesis strategies and ligand selection for MOF-based composite materials.It then analyzes the advantages of origin-al MOFs and their derived materials,such as carbon materials and metal compounds,in enhancing LIC performance.Finally,the re-view discusses the major challenges faced by MOFs and their derivatives in LIC applications and offers future research directions and recommendations.关键词
锂离子电容器/MOFs/过渡金属氧化物/能量密度/功率密度Key words
Lithium-ion capacitors/MOFs/Transition metal oxide/Energy density/Power density分类
化学化工引用本文复制引用
赵沙沙,张熊,李晨,安亚斌,胡涛,王凯,孙现众,马衍伟..金属有机框架及其衍生物在锂离子电容器中的应用[J].新型炭材料（中英文）,2024,39(5):872-895,24.
